Mossbauer studies for La-Co substituted strontium ferrite

被引:30
作者
Choi, Dong Hyeok [1 ]
Lee, Sang Won [1 ]
Shim, In-Bo [1 ]
Kim, Chul Sung [1 ]
机构
[1] Kookmin Univ, Dept Phys, Seoul 136702, South Korea
关键词
Sr ferrite; Mossbauer; Site occupancy;
D O I
10.1016/j.jmmm.2006.01.151
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
La-Co substituted Sr ferrite (La-Co)(x)Sr-1 Fe-x(12) O-x(19) (x = 00-0.4) powders synthesized by sol-gel process were investigated for their magnetic properties. The crystalline structures were characterized by X-ray diffractometer (XRD), and magnetic properties were measured by vibrating sample magnetometer (VSM) and Mossbauer spectrometer. The crystalline structure of (La-Co)(x)Sr1-xFe12-xO19 (x = 0.0-0.4) was single M-type hexagonal phase. Magnetization under an applied maximum field of 15 kOe was measured 63.9 emu/g for x = 0.0, and decreased gradually for x = 0.2, and increased slightly over x = 0.2. Coercivity, H-C, measured 7.5 kOe of maximum value for x = 0.2. With increasing x, we interpret that it is closely related to La-Co occupation of 4f(2) and 12k sites from the analysis of Mossbauer spectra. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:E243 / E245
页数:3
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