Formation, atomic structures and properties of boron nitride and carbon nanocage fullerene materials

被引：265
作者：
Oku, T [1 ]
Kuno, M [1 ]
Kitahara, H [1 ]
Narita, I [1 ]
机构：
[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan
来源：
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS | 2001年 / 3卷 / 07期
关键词：
fullerenes; electron microscopy; scanning tunneling microscopy (STM); microstructure;
D O I：
10.1016/S1466-6049(01)00169-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Various boron nitride (BN) and carbon (C) nanocage fullerene materials (clusters, metallofullerenes, onion, nanotubes and nanocapsules) were synthesized by arc-melting, electron-beam irradiation, chemical reaction, and self-organization. Atomic structures and structural stability of these materials were investigated by high-resolution electron microscopy, energy dispersive spectroscopy, electron energy-loss spectroscopy, molecular mechanics, molecular dynamics and molecular orbital calculations. Photoluminescence, magnetic and electronic properties of these fullerene materials were also investigated. The present work indicates that: the new BN and C nanocage fullerene materials with various atomic structures and properties can be produced by various synthesis methods, and a guideline for designing the BN and C fullerene materials is summarized. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：597 / 612
页数：16
相关论文
共 54 条
  • [31] Atomic structure of Pd-intercalated graphite by high-resolution electron microscopy and first principles calculations
    Oku, T
    Sun, Q
    Wang, DS
    Wang, Q
    Kawazoe, Y
    Schmid, G
    Suganuma, K
    [J]. MATERIALS TRANSACTIONS JIM, 1999, 40 (11): : 1213 - 1218
  • [32] Digital HREM imaging of yttrium atoms in YB56 with YB66 structure
    Oku, T
    Carlsson, A
    Wallenberg, LR
    Malm, JO
    Bovin, JO
    Higashi, I
    Tanaka, T
    Ishizawa, Y
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1998, 135 (02) : 182 - 193
  • [33] Formation and structure of carbon nanocage structures produced by polymer pyrolysis and electron-beam irradiation
    Oku, T
    Hirano, T
    Suganuma, K
    Nakajima, S
    [J]. JOURNAL OF MATERIALS RESEARCH, 1999, 14 (11) : 4266 - 4273
  • [34] Formation of carbon nanocapsules with SiC nanoparticles prepared by polymer pyrolysis
    Oku, T
    Niihara, K
    Suganuma, K
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (06) : 1323 - 1325
  • [35] One-dimensional positioning of carbon nanocapsules and spontaneous formation of carbon nanotubes by self-organization of gold nanoparticles
    Oku, T
    Suganuma, K
    [J]. MICROELECTRONIC ENGINEERING, 2000, 51-2 : 51 - 60
  • [36] Surface structures of (Hg,Tl)-based oxides studied by high-resolution electron microscopy
    Oku, T
    Nakajima, S
    [J]. SURFACE SCIENCE, 1998, 407 (1-3) : L647 - L651
  • [37] Synthesis, atomic structures and properties of carbon and boron nitride fullerene materials
    Oku, T
    Hirano, T
    Kuno, M
    Kusunose, T
    Niihara, K
    Suganuma, K
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 74 (1-3): : 206 - 217
  • [38] OKU T, 2001, UNPUB DIAMOND RELAT
  • [39] Identifying the forces responsible for self-organization of nanostructures at crystal surfaces
    Pohl, K
    Bartelt, MC
    de la Figuera, J
    Bartelt, NC
    Hrbek, J
    Hwang, RQ
    [J]. NATURE, 1999, 397 (6716) : 238 - 241
  • [40] FULLERENES, NANOTUBES, ONIONS AND RELATED CARBON STRUCTURES
    RAO, CNR
    SESHADRI, R
    GOVINDARAJ, A
    SEN, R
    [J]. MATERIALS SCIENCE & ENGINEERING R-REPORTS, 1995, 15 (06) : 209 - 262
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