Formation, atomic structures and properties of boron nitride and carbon nanocage fullerene materials

被引：265
作者：
Oku, T [1 ]
Kuno, M [1 ]
Kitahara, H [1 ]
Narita, I [1 ]
机构：
[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan
来源：
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS | 2001年 / 3卷 / 07期
关键词：
fullerenes; electron microscopy; scanning tunneling microscopy (STM); microstructure;
D O I：
10.1016/S1466-6049(01)00169-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Various boron nitride (BN) and carbon (C) nanocage fullerene materials (clusters, metallofullerenes, onion, nanotubes and nanocapsules) were synthesized by arc-melting, electron-beam irradiation, chemical reaction, and self-organization. Atomic structures and structural stability of these materials were investigated by high-resolution electron microscopy, energy dispersive spectroscopy, electron energy-loss spectroscopy, molecular mechanics, molecular dynamics and molecular orbital calculations. Photoluminescence, magnetic and electronic properties of these fullerene materials were also investigated. The present work indicates that: the new BN and C nanocage fullerene materials with various atomic structures and properties can be produced by various synthesis methods, and a guideline for designing the BN and C fullerene materials is summarized. (C) 2001 Elsevier Science Ltd. All rights reserved.
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收藏
页码：597 / 612
页数：16
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