Degradation of Solid Oxide Electrolyzer Cells with Different Anodes

被引:9
作者
Xu, C. [1 ]
Wang, Y. [1 ]
Jin, L. [1 ]
Ding, J. -F. [1 ]
Ma, X. [1 ]
Wang, W. G. [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Div Fuel Cell & Energy Technol, Ningbo 315201, Zhejiang, Peoples R China
来源
ELECTROCHEMICAL SYNTHESIS OF FUELS 1 | 2012年 / 41卷 / 33期
关键词
TEMPERATURE; PERFORMANCE;
D O I
10.1149/1.3702416
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Solid oxide electrolyzer cells (SOECs) have been considered effective to produce hydrogen at a high conversion efficiency through high temperature electrolysis (HTE) process and has a potential to scale up to a large-scale economy hydrogen source. The crucial issue for the SOEC moving into practical applications is stability. In this paper, investigation was conducted with the focus on the anode degradation using SOEC cells with strontium doped lanthanum manganite (LSM) anode and strontium doped lanthanum ferro-cobaltites (LSCF) anode. The results showed a more stable performance in LSM cells than LSCF cells when testing at 750 degrees C anode degradation and anode delamination contributed most of performance drop. The LSM cell is thus more suitable for HTE than the LSCF cell due to its better bonding between the electrolyte and anode.
引用
收藏
页码:97 / 102
页数:6
相关论文
共 11 条
  • [1] [Anonymous], METALLURGY
  • [2] High temperature water electrolysis in solid oxide cells
    Brisse, Annabelle
    Schefold, Josef
    Zahid, Mohsine
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (20) : 5375 - 5382
  • [3] Performance and durability of solid oxide electrolysis cells
    Hauch, A.
    Jensen, S. H.
    Ramousse, S.
    Mogensen, M.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (09) : A1741 - A1747
  • [4] Polarization effects in intermediate temperature, anode-supported solid oxide fuel cells
    Kim, JW
    Virkar, AV
    Fung, KZ
    Mehta, K
    Singhal, SC
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) : 69 - 78
  • [5] Electrolyte degradation in anode supported microtubular yttria stabilized zirconia-based solid oxide steam electrolysis cells at high voltages of operation
    Laguna-Bercero, M. A.
    Campana, R.
    Larrea, A.
    Kilner, J. A.
    Orera, V. M.
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (21) : 8942 - 8947
  • [6] Performance of solid oxide electrolysis cells based on scandia stabilised zirconia
    Laguna-Bercero, M. A.
    Skinner, S. J.
    Kilner, J. A.
    [J]. JOURNAL OF POWER SOURCES, 2009, 192 (01) : 126 - 131
  • [7] Electrode performance in reversible solid oxide fuel cells
    Marina, O. A.
    Pederson, L. R.
    Williams, M. C.
    Coffey, G. W.
    Meinhardt, K. D.
    Nguyen, C. D.
    Thomsen, E. C.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (05) : B452 - B459
  • [8] Solid oxide fuel cells for stationary, mobile, and military applications
    Singhal, SC
    [J]. SOLID STATE IONICS, 2002, 152 : 405 - 410
  • [9] Mechanism of oxygen electrode delamination in solid oxide electrolyzer cells
    Virkar, Anil V.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (18) : 9527 - 9543
  • [10] Xu C., 2009, EUROPEAN FUEL CELL F, P14