Ammonia sensor based on NASICON and Cr2O3 electrode

被引:69
作者
Liang, Xishuang [1 ]
Zhong, Tiegang [1 ]
Guan, Hesong [1 ]
Liu, Fengmin [1 ]
Lu, Geyu [1 ]
Quan, Baofu [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect Jilin Univ Reg, Changchun 130012, Peoples R China
关键词
NH3; NASICON; Cr2O3; Gas sensor; STABILIZED ZIRCONIA; COMBINING NASICON; ROOM-TEMPERATURE; OXIDE ELECTRODE; NH3; GAS; FILM; POLYANILINE;
D O I
10.1016/j.snb.2008.11.028
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A compact tubular sensor based on NASICON (sodium super ionic conductor) and porous Cr2O3 sensing electrode was designed for the detection of ammonia. The sensor gave excellent sensing properties to 50-500 ppm ammonia in air at 250-450 C. The EMF value of the sensor was almost proportional to the logarithm of ammonia concentration, the sensitivity (slope) was -89 mV/decade at 350 C. It was also seen that the sensor showed a good selectivity to ammonia, and an excellent resistance to water vapor, The sensor had speedy response kinetics to ammonia, the 90% response time to 50 ppm ammonia was 30 s, and the recovery time was 60 s. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:479 / 483
页数:5
相关论文
共 14 条
[1]   Application of conducting polyaniline as sensor material for ammonia [J].
Dhawan, SK ;
Kumar, D ;
Ram, MK ;
Chandra, S ;
Trivedi, DC .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 40 (2-3) :99-103
[2]  
FUA T, 2008, SENSOR ACTUAT B-CHEM, V129, P339
[3]   Highly sensitive and selective room temperature NH3 gas microsensor using an ionic conductor (CuBr) film [J].
Lauque, P ;
Bendahan, M ;
Seguin, JL ;
Ngo, KA ;
Knauth, P .
ANALYTICA CHIMICA ACTA, 2004, 515 (02) :279-284
[4]   Solid-state potentiometric SO2 sensor combining NASICON with V2O5-doped TiO2 electrode [J].
Liang, Xishuang ;
Zhong, Tiegang ;
Quan, Baofu ;
Wang, Biao ;
Guan, Hesong .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 134 (01) :25-30
[5]   Solid-state potentiometric H2S sensor combining NASICON with Pr6O11-doped SnO2 electrode [J].
Liang, Xishuang ;
He, Yuehua ;
Liu, Fengrnin ;
Wang, Biao ;
Zhong, Tiegang ;
Quan, Baofu ;
Lu, Geyu .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 125 (02) :544-549
[6]   High-temperature sensors for NO and NO2 based on stabilized zirconia and spinel-type oxide electrodes [J].
Lu, G ;
Miura, N ;
Yamazoe, N .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (08) :1445-1449
[7]   High-temperature hydrogen sensor based on stabilized zirconia and a metal oxide electrode [J].
Lu, GY ;
Miura, N ;
Yamazoe, N .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 35 (1-3) :130-135
[8]   Effect of NH3 gas on the electrical conductivity of polyaniline blend films [J].
Matsuguchi, M ;
Io, J ;
Sugiyama, G ;
Sakai, Y .
SYNTHETIC METALS, 2002, 128 (01) :15-19
[9]   SO2-sensing characteristics of Nasicon sensors with Na2SO4-BaSO4 auxiliary electrolytes [J].
Min, BY ;
Choi, SD .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :209-213
[10]   Cr2O3-activated ZnO thick film resistors for ammonia gas sensing operable at room temperature [J].
Patil, D. R. ;
Patil, L. A. ;
Patil, P. P. .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 126 (02) :368-374