Metal-Organic Frameworks against Toxic Chemicals

被引：556

作者：

Islamoglu, Timur ^{[1
,2
]}

Chen, Zhijie ^{[1
,2
]}

Wasson, Megan C. ^{[1
,2
]}

Buru, Cassandra T. ^{[1
,2
]}

Kirlikovali, Kent O. ^{[1
,2
]}

Afrin, Unjila ^{[1
,2
]}

Mian, Mohammad Rasel ^{[1
,2
]}

Farha, Omar K. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA

来源：

CHEMICAL REVIEWS | 2020年 / 120卷 / 16期

关键词：

SELECTIVE CATALYTIC-REDUCTION; UNDERSTANDING REACTIVE ADSORPTION; NITRIC-OXIDE ADSORPTION; CARBON-DIOXIDE; WARFARE AGENTS; AMMONIA CAPTURE; RETICULAR CHEMISTRY; HYDROGEN-SULFIDE; HIGH-CAPACITY; SULFUR-DIOXIDE;

D O I：

10.1021/acs.chemrev.9b00828

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal-organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.

引用

页码：8130 / 8160

页数：31

共 233 条

[61] Using molecular simulation to characterise metal-organic frameworks for adsorption applications [J].