A twofold interpenetrating 3D Keggin-based Ag(I) complex based on a flexible bis-pyridyl-bis-amide

被引：6

作者：

Wang, Xiuli ^{[1
]}

Xu, Chuang ^{[1
]}

Lin, Hongyan ^{[1
]}

Liu, Guocheng ^{[1
]}

Luan, Jian ^{[1
]}

Chang, Zhihan ^{[1
]}

Tian, Aixiang ^{[1
]}

机构：

[1] Bohai Univ, Dept Chem, Liaoning Prov Silicon Mat Engn Technol Res Ctr, Jinzhou, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Keggin polyoxometalate; Metal-organic complex; Interpenetrating network; Flexible bis-pyridyl-bis-amide ligand; METAL-ORGANIC FRAMEWORK; WELLS-DAWSON POLYOXOMETALATE; COORDINATION POLYMERS; STRUCTURAL DIVERSITY; DIAMONDOID NETWORK; CRYSTAL-STRUCTURE; CLUSTERS; ARCHITECTURES; TOPOLOGY; CHAIN;

D O I：

10.1080/00958972.2013.783697

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Keggin-type polyoxometalate (POM)-based complex, [Ag-5(L)(3) (H2O)(2)]center dot 6H(2)O (1) (L=N,N-bis(3-pyridinecarboxamide)-1,2-ethane), has been hydrothermally synthesized. Compound 1 shows a 3D+3D interpenetrating network with a (3,4,4,4)-connected (4x6(2))(2)(4(2)x6(2)x8(2))(6(5)x8)(2) topology, and it represents the first example of interpenetrating POM-based complex based on flexible bis-pyridyl-bis-amide ligands. Moreover, the electrochemical behavior and luminescence of 1 have been investigated.

引用

页码：1451 / 1458

页数：8

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