Synthesis of an anionically chargeable, high-molar-mass, second-generation dendronized polymer and the observation of branching by scanning force microscopy

被引:52
作者
Kasëmi, E
Zhuang, W
Rabe, JP
Fischer, K
Schmidt, M
Colussi, M
Keul, H
Yi, D
Cölfen, H
Schlüter, AD
机构
[1] Humboldt Univ, Dept Phys, D-12489 Berlin, Germany
[2] ETH Honggerberg, Dept Mat, Inst Polymers, Swiss Fed Inst Technol, CH-8093 Zurich, Switzerland
[3] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55099 Mainz, Germany
[4] Rhein Westfal TH Aachen, Inst Tech & Macromol Chem, D-52056 Aachen, Germany
[5] Max Planck Inst Colloids & Interfaces, D-14476 Golm, Germany
关键词
D O I
10.1021/ja057964g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient synthesis of a methacrylate-based, second-generation (G2) dendronized macromonomer and its free radical polymerization to the corresponding high-molar-mass G2 dendronized polymer are described. The molar mass is determined by gel permeation chromatography (GPC), light-scattering, and analytical ultracentrifugation and compared with values estimated from a scanning force microscopy (SFM) contour lengths analysis of individualized polymer strands on mica. The polymer carries terminal tert-butyl-protected carboxyl groups, the degree of deprotection of which with trifluoroacetic acid is quantified by NMR spectroscopy using the highest molar mass sample. SFM imaging of both protected (noncharged) and unprotected (charged) dendronized polymers on solid substrates reveals mostly linear chains but also some with main-chain branches. The nature of these branches is investigated and the degree roughly estimated to which they are formed. Finally, a synthetic model experiment is described which sheds some light on the aspect of whether chain transfer, a process that could lead to covalent branching, is of importance in the synthesis of the present dendronized polymers.
引用
收藏
页码:5091 / 5099
页数:9
相关论文
共 61 条
[1]   Poly(phenylenevinylene)s with dendritic side chains: Synthesis, self-ordering, and liquid crystalline properties [J].
Bao, ZN ;
Amundson, KR ;
Lovinger, AJ .
MACROMOLECULES, 1998, 31 (24) :8647-8649
[2]   Covalent connection of two individual polymer chains on a surface:: An elementary step towards molecular nanoconstructions [J].
Barner, J ;
Mallwitz, F ;
Shu, LJ ;
Schlüter, AD ;
Rabe, JP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (17) :1932-1935
[3]  
BARNER J, UNPUB
[4]   A SCANNING MICHELSON INTERFEROMETER FOR THE MEASUREMENT OF THE CONCENTRATION AND TEMPERATURE DERIVATIVE OF THE REFRACTIVE-INDEX OF LIQUIDS [J].
BECKER, A ;
KOHLER, W ;
MULLER, B .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1995, 99 (04) :600-608
[5]   Synthesis of molecular brushes with block copolymer side chains using atom transfer radical polymerization [J].
Börner, HG ;
Beers, K ;
Matyjaszewski, K ;
Sheiko, SS ;
Möller, M .
MACROMOLECULES, 2001, 34 (13) :4375-4383
[6]   Double-helical ultrastructure of polycationic dendronized polymers determined by single-particle cryo-TEM [J].
Böttcher, C ;
Schade, B ;
Ecker, C ;
Rabe, JP ;
Shu, LJ ;
Schlüter, AD .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (10) :2923-2928
[7]   MSTARA and MSTARI: Interactive PC algorithms for simple, model independent evaluation of sedimentation equilibrium data [J].
Colfen, H ;
Harding, SE .
EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERS, 1997, 25 (5-6) :333-346
[8]   Cylindrical molecular brushes [J].
Dziezok, P ;
Sheiko, SS ;
Fischer, K ;
Schmidt, M ;
Möller, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (24) :2812-2815
[9]  
EDELSTEIN SJ, 1967, J BIOL CHEM, V242, P306
[10]  
Fischer K, 2001, MACROMOL RAPID COMM, V22, P787, DOI 10.1002/1521-3927(20010701)22:10<787::AID-MARC787>3.0.CO