Synthesis, spectroscopic and thermal investigations of solid charge-transfer complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane and the acceptors iodine, TCNE, TCNQ and chloranil

被引：33

作者：

AlQaradawi, Siham Y. ^{[1
]}

Bazzi, Hassan S. ^{[2
]}

Mostafa, Adel ^{[2
]}

Nour, El-Metwally ^{[1
]}

机构：

[1] Qatar Univ, Coll Arts & Sci, Dept Chem & Earth Sci, Doha, Qatar

[2] Texas A&M Univ, Dept Chem, Doha, Qatar

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2008年 / 71卷 / 04期

关键词：

1,4,7-Trimethyl-1,4,7-triazacyclononane; Iodine; TCNE; TCNQ; Solid CT-complexes; Infrared; Thermal; Structure;

D O I：

10.1016/j.saa.2008.06.010

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The solid charge-transfer complexes formed in the reaction of the electron donor 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) with the acceptors iodine, tetracyanoethylene (TCNE) and 7,7,8,8-tetracyanoquinodimethane (TCNQ) have been isolated. These were characterized through electronic and infrared spectra as well as thermal and elemental analysis. The results show that the formed solid CT-complexes have the formulas [(TMTACN)I]I(3), [(TMTACN)(TCNE)(5)] and [(TMTACN)(TCNQ)(3)] in full agreement with the known reaction stoichiometries in solution. The chloranil Cr-solid complex cannot be isolated in pure form. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1594 / 1598

页数：5

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