Enhancement of the initial hydrogenation of Mg by ball milling with alkali metal amides MNH2 (M = Li or Na)

被引:11
作者
Chu, Hailiang [1 ,2 ]
Qiu, Shujun [1 ,2 ]
Sun, Lixian [1 ,2 ]
Huot, Jacques [3 ]
机构
[1] Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China
[2] Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
[3] Univ Quebec Trois Rivieres, Hydrogen Res Inst, Trois Rivieres, PQ G9A 5H7, Canada
基金
中国国家自然科学基金;
关键词
SORPTION PROPERTIES; DESORPTION PROPERTIES; STORAGE; MAGNESIUM; SYSTEM; ABSORPTION; ACTIVATION; ALLOYS; NANOSTRUCTURES; PERFORMANCE;
D O I
10.1039/c5dt01847a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The introduction of 4 wt% of MNH2 (M = Li, Na) and other additives (Li, MgH2, NaCl, and NaBr) into pure Mg by ball milling greatly enhances the first hydrogenation (activation). Under 2 MPa of H-2 at 608 K, the best activation performance is achieved with the NaNH2 additive.
引用
收藏
页码:16694 / 16697
页数:4
相关论文
共 35 条
[1]   Effect of cold rolling on hydrogen sorption properties of die-cast and as-cast magnesium alloys [J].
Amira, S. ;
Huot, J. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 520 :287-294
[2]   Synthesis and characterization of amide-borohydrides: New complex light hydrides for potential hydrogen storage [J].
Chater, Philip A. ;
Anderson, Paul A. ;
Prendergast, James W. ;
Walton, Allan ;
Mann, Vicky S. J. ;
Book, David ;
David, William I. F. ;
Johnson, Simon R. ;
Edwards, Peter P. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 446 :350-354
[3]   Interaction between lithium amide and lithium hydride [J].
Chen, P ;
Xiong, ZT ;
Luo, JZ ;
Lin, JY ;
Tan, KL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (39) :10967-10970
[4]   Interaction of hydrogen with metal nitrides and imides [J].
Chen, P ;
Xiong, ZT ;
Luo, JZ ;
Lin, JY ;
Tan, KL .
NATURE, 2002, 420 (6913) :302-304
[5]   Efficient hydrogen storage with the combination of lightweight Mg/MgH2 and nanostructures [J].
Cheng, Fangyi ;
Tao, Zhanliang ;
Liang, Jing ;
Chen, Jun .
CHEMICAL COMMUNICATIONS, 2012, 48 (59) :7334-7343
[6]   Hydrogen storage properties of Li-Ca-N-H system with different molar ratios of LiNH2/CaH2 [J].
Chu, Hailiang ;
Xiong, Zhitao ;
Wu, Guotao ;
He, Teng ;
Wu, Chengzhang ;
Chen, Ping .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (15) :8317-8321
[7]   Synthesis, structural and hydrogenation properties of Mg-rich MgH2-TiH2 nanocomposites prepared by reactive ball milling under hydrogen gas [J].
Cuevas, Fermin ;
Korablov, Dmytro ;
Latroche, Michel .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (03) :1200-1211
[8]   Mg-TM (TM: Ti, Nb, V, Co, Mo or Ni) core-shell like nanostructures: synthesis, hydrogen storage performance and catalytic mechanism [J].
Cui, Jie ;
Liu, Jiangwen ;
Wang, Hui ;
Ouyang, Liuzhang ;
Sun, Dalin ;
Zhu, Min ;
Yao, Xiangdong .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (25) :9645-9655
[9]   Investigation on the synthesis, characterization and hydrogenation behaviour of new Mg-based composite materials Mg-x wt.% MmNi4.6Fe0.4 prepared through mechanical alloying [J].
Davidson, DJ ;
Raman, SSS ;
Srivastava, ON .
JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 292 (1-2) :194-201
[10]   Cold rolling under inert atmosphere: A powerful tool for Mg activation [J].
Floriano, R. ;
Leiva, D. R. ;
Carvalho, J. A. ;
Ishikawa, T. T. ;
Botta, W. J. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (10) :4959-4965