Synthesis, Characterization, and Reactivity of Mononuclear O,N-Chelated Vanadium(V) and -(IV) Complexes [VO(acac)2(SA)] and [VO(acac)(MP)]

被引：1

作者：

Hou, Jin-Long ^{[1
]}

Bi, Ye ^{[1
]}

Wu, Hong-Yuan ^{[1
]}

Han, Cheng-Li ^{[1
]}

机构：

[1] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2013年 / 43卷 / 09期

关键词：

crystal structures; mononuclear complexes; oxovanadium complexes; self-assembly; OXOVANADIUM(IV); DERIVATIVES; REDUCTION; CHEMISTRY; TOXICITY; LIGAND;

D O I：

10.1080/15533174.2012.756907

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of one equivalent each of [VO(acac)(2)] with salicylic acid (HSA) and 2-methyl-6-[(2-morpholin-4-ylethylimino) methyl]phenol (HMP; derived from 2-hydroxy-3-methylbenzal dehyde and 2-morpholin-4-ylethylamine) in methanol under aerobic conditions provide two mononuclear O,N-chelated vanadium (V) and -(IV) complexes [VO(acac)(2)(SA)] (1) and [VO(acac)(MP)] (2). The complexes have been characterized by analytical and spectroscopic measurements. The structures of the complexes have been determined by X-ray crystallography. In both complexes, the metal centers are in distorted octahedral coordination spheres. The SA ligand coordinates the metal ion through one carboxylate oxygen, and the MP ligand coordinates the metal ion through the imine-N, the phenolate-O, and the morpholin-N atoms in a meridional fashion. The remaining three coordinate sites are occupied by the bidentate O,O-donor acetylacetonate (acac) and the oxo group.

引用

页码：1236 / 1240

页数：5

共 22 条

[1] Chemistry and insulin-mimetic properties of bis(acetylacetonate)oxovanadium(IV) and derivatives [J].

Amin, SS ;

Cryer, K ;

Zhang, BY ;

Dutta, SK ;

Eaton, SS ;

Anderson, OP ;

Miller, SM ;

Reul, BA ;

Brichard, SM ;

Crans, DC .

INORGANIC CHEMISTRY, 2000, 39 (03) :406-416

[2]

Berry RE, 1999, ANGEW CHEM INT EDIT, V38, P795, DOI 10.1002/(SICI)1521-3773(19990315)38:6<795::AID-ANIE795>3.0.CO

[3]

2-7

[4] Synthesis, characterization, and reactivity of mononuclear O,N-chelated vanadium(IV) and -(III) complexes of methyl 2-aminocyclopent-1-ene-1-dithlocarboxylate based ligand: Reporting an example of conformational isomerism in the solid state [J].

Bhattacharyya, S ;

Mukhopadhyay, S ;

Samanta, S ;

Weakley, TJR ;

Chaudhury, M .

INORGANIC CHEMISTRY, 2002, 41 (09) :2433-2440

[5] INSERTION OF OXYGEN INTO VANADIUM-CARBON BONDS - FORMATION OF [(MU-ETA-3-C5ME5O3)V(O)]2 FROM (ETA-C5ME5)2V AND O2 [J].

BOTTOMLEY, F ;

MAGILL, CP ;

WHITE, PS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :3070-3071

[6]

Bruker, 2003, SMART VERS 5 63 SAIN

[7] IRON EXAFS OF AZOTOBACTER-VINELANDII NITROGENASE MO-FE AND V-FE PROTEINS [J].

CHEN, J ;

CHRISTIANSEN, J ;

TITTSWORTH, RC ;

HALES, BJ ;

GEORGE, SJ ;

COUCOUVANIS, D ;

CRAMER, SP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) :5509-5515

[8] How environment affects drug activity: Localization, compartmentalization and reactions of a vanadium insulin-enhancing compound, dipicolinatooxovanadium(V) [J].

Crans, Debbie C. ;

Trujillo, Alejandro M. ;

Pharazyn, Philip S. ;

Cohen, Mitchell D. .

COORDINATION CHEMISTRY REVIEWS, 2011, 255 (19-20) :2178-2192

[9] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

[10] CIS-DIOXO(ACETYLACETONATO) (1,10-PHENANTHROLINE)VANADIUM (V) [J].

ISOBE, K ;

OOI, S ;

NAKAMURA, Y ;

KAWAGUCHI, S ;

KUROYA, H .

CHEMISTRY LETTERS, 1975, (01) :35-38

← 1 2 3 →