catena-Poly[[[2-(2-chlorophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ2N′,O]copper(II)]-μ-morpholine-κ2N:O]

被引:5
作者
Wang, Min [1 ]
Lian, Zhao-Xun [2 ]
机构
[1] Beijing Technol & Business Univ, Sch Sci, Beijing Key Lab Plant Resources Res & Dev, Beijing 102488, Peoples R China
[2] Henan Inst Sci & Technol, Sch Chem & Chem Engn, Xinxiang 453003, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2013年 / 69卷
关键词
CRYSTAL-STRUCTURE; SUPRAMOLECULAR NETWORKS; COMPLEXES; CYTOTOXICITY; ANALOGS;
D O I
10.1107/S0108270113011967
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, {[Cu(C15H11ClN2O3)(C4H9NO)](n), the Cu-II cation has square-pyramidal geometry. The morpholine ligand serves as a bridge to link two symmetry-related metal atoms, resulting in an infinite chain structure along the a axis. Adjacent chains are extended into a two-dimensional layered structure via hydrogen bonds formed between morpholine and amide N atoms [N-H center dot center dot center dot N = 2.971 (3) angstrom].
引用
收藏
页码:594 / +
页数:8
相关论文
共 23 条
[1]   Cytotoxicity of salicylaldehyde benzoylhydrazone analogs and their transition metal complexes: quantitative structure-activity relationships [J].
Ainscough, EW ;
Brodie, AM ;
Denny, WA ;
Finlay, GJ ;
Gothe, SA ;
Ranford, JD .
JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 77 (3-4) :125-133
[2]   Synthesis and spectroscopic characterization of [CoIII(salophen)(amine)2]ClO4 (amine = morpholine, pyrrolidine, and piperidine) complexes.: The crystal structures of [CoIII(salophen)(morpholine)2]ClO4 and [CIII(salophen)(pyrrolidine)2]ClO4 [J].
Amirnasr, M ;
Schenk, KJ ;
Gorji, A ;
Vafazadeh, R .
POLYHEDRON, 2001, 20 (7-8) :695-702
[3]  
[Anonymous], 2010, DIAMOND
[4]  
Bruker, 2007, SADABS SMART SAINT
[5]   (Acetylacetonato-κ2O,O′)(dimethylformamide-κO)[2-phenoxyethanal (2-oxidobenzylidene)hydrazonato-κ3O,N,O′]cobalt(III) [J].
Chen, Xiao-Hua ;
Liu, Shi-Xiong .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 :M2869-M2871
[6]   Nickel and zinc complexes with a monodentate heterocycle and tridentate Schiff base ligands: self-assembly to one- and two-dimensional supramolecular networks via hydrogen bonding [J].
Chen, Xiao-Hua ;
Wu, Qiong-Jie ;
Liang, Zhi-Yu ;
Zhan, Chun-Rong ;
Liu, Jian-Bin .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2009, 65 :M190-M194
[7]   Complexes of salicylaldehyde acylhydrazones:: Cytotoxicity, QSAR and crystal structure of the sterically hindered t-butyl dimer [J].
Koh, LL ;
Kon, OL ;
Loh, KW ;
Long, YC ;
Ranford, JD ;
Tan, ALC ;
Tjan, YY .
JOURNAL OF INORGANIC BIOCHEMISTRY, 1998, 72 (3-4) :155-162
[8]   Hybrid Polymeric Iodoplumbates Constructed from Morpholine and Its Derivatives: Structures and Properties [J].
Li, Hao-Hong ;
Chen, Zhi-Rong ;
Cheng, Li-Chuan ;
Wang, Yun-Jie ;
Feng, Miao ;
Wang, Min .
DALTON TRANSACTIONS, 2010, 39 (45) :11000-11007
[9]  
Li WP, 2004, CHINESE J STRUC CHEM, V23, P1432
[10]  
Lian ZX, 2008, CHINESE J STRUC CHEM, V27, P639