Conversion of levulinic acid into γ-valerolactone using Fe3(CO)12: mimicking a biorefinery setting by exploiting crude liquors from biomass acid hydrolysis

被引：54
作者：
Metzker, Gustavo [1 ]
Burtoloso, Antonio C. B. [1 ,2 ]
机构：
[1] Univ Sao Paulo, Chem Inst Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
[2] Brazilian Bioethanol Sci & Technol Lab CTBE CNPEM, BR-13083970 Campinas, SP, Brazil
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 75期
基金：
巴西圣保罗研究基金会;
关键词：
CATALYZED TRANSFER HYDROGENATION; NONENZYMATIC SUGAR PRODUCTION; FORMIC-ACID; LIGNOCELLULOSIC BIOMASS; TRIIRON DODECACARBONYL; THERMAL-DECOMPOSITION; MOLECULAR-STRUCTURE; IRON NANOPARTICLES; HYDROCARBON FUELS; ORGANIC-SYNTHESIS;
D O I：
10.1039/c5cc02993g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The conversion of biomass-derived levulinic acid (LA) into gamma-valerolactone (GVL) using formic acid (FA) and Fe-3(CO)(12) as the catalyst precursor was achieved in 92% yield. To mimic a biorefinery setting, crude liquor (containing 20% LA) from the acid hydrolysis of sugarcane biomass in a pilot plant facility was directly converted into GVL in good yield (50%), without the need for isolating LA.
引用
收藏
页码：14199 / 14202
页数：4
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