Construction of a Set of Cadmium(II) Coordination Polymers with Atza and 2,2′-Bipy or 1,10-Phen Ligands (Atza=5-Aminotetrazole-1-acetato Anion)

被引：0
作者：
Li Qiao-Yun [1 ]
He Ming-Hua [1 ]
Jin Jian-Ning [1 ]
Shen Wei [1 ]
Yang Jie [1 ]
Yang Gao-Wen [1 ]
Zhu Lin-Liu [1 ]
Dai Jian [1 ]
机构：
[1] Changshu Inst Technol, Dept Chem & Mat Engn, Jiangsu Lab Adv Funct Mat, Changshu 215500, Jiangsu, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2012年 / 31卷 / 07期
关键词：
Cd(II); 5-aminotetrazole-1-acetato; 2,2 '-bipy/1,10-phen; coordination polymers; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; HYDROGEN STORAGE; COMPLEXES; COPPER(II); FRAMEWORKS; CHEMISTRY; ZINC(II); UNITS; ACID;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of CdX2 (X = NO3-, ClO4-) with Hatza (atza = 5-aminotetrazole-1-acetato anion) and 2,2'-bipyridine (2,2'-bipy) or 1,10-phenanthroline (1,10-phen) in a methanol/aqueous solution produced a set of new Cd(II) coordination polymers, {[Cd(atza)(H2O)(2,2'-bipy)]ClO4}(n) (1), {[Cd(atza)(H2O)(1,10-phen)]ClO4}(n) (2), {[Cd(atza)(H2O)(2,2'-bipy)]NO3}(n) (3) and {[Cd(atza)(2)(1,10-phen)]center dot 0.5H(2)O}(n) (4). Single-crystal X-ray diffraction analysis reveals that each Cd(II) ion has a distorted octahedral coordination geometry in 1-4, and the Cd(II) ion centers are connected through the tridentate atza bridging ligands to form a 2D layer (1-3) or 1D chain (4) structure. The fluorescent properties of 2 and 4 are also discussed.
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页码：1047 / 1055
页数：9
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