Stereoselective intramolecular cyclopropanation through catalytic olefin activation

被引：63
作者：
Huang, Xueliang [1 ]
Klimczyk, Sebastian [1 ]
Veiros, Luis F. [2 ]
Maulide, Nuno [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, Mulheim, Germany
[2] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
来源：
CHEMICAL SCIENCE | 2013年 / 4卷 / 03期
关键词：
ALPHA-AMINO-ACIDS; OXIDATIVE CYCLIZATION; UNACTIVATED ALKENES; NATURAL OCCURRENCE; EFFICIENT ACCESS; CARBENE-TRANSFER; GOLD; HYDROAMINATION; CYCLOISOMERIZATION; COMPLEXES;
D O I：
10.1039/c2sc21914j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel stereoselective and convergent catalytic method for the cyclopropanation of electron-neutral and -rich olefins by sulfonium ylides is reported which unusually proceeds through olefin activation rather than by metal carbene formation.
引用
收藏
页码：1105 / 1110
页数：6
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