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Stereoselective intramolecular cyclopropanation through catalytic olefin activation
被引:63
作者
:
Huang, Xueliang
论文数:
0
引用数:
0
h-index:
0
机构:
Max Planck Inst Kohlenforsch, Mulheim, Germany
Max Planck Inst Kohlenforsch, Mulheim, Germany
Huang, Xueliang
[
1
]
Klimczyk, Sebastian
论文数:
0
引用数:
0
h-index:
0
机构:
Max Planck Inst Kohlenforsch, Mulheim, Germany
Max Planck Inst Kohlenforsch, Mulheim, Germany
Klimczyk, Sebastian
[
1
]
Veiros, Luis F.
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
Max Planck Inst Kohlenforsch, Mulheim, Germany
Veiros, Luis F.
[
2
]
Maulide, Nuno
论文数:
0
引用数:
0
h-index:
0
机构:
Max Planck Inst Kohlenforsch, Mulheim, Germany
Max Planck Inst Kohlenforsch, Mulheim, Germany
Maulide, Nuno
[
1
]
机构
:
[1]
Max Planck Inst Kohlenforsch, Mulheim, Germany
[2]
Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
来源
:
CHEMICAL SCIENCE
|
2013年
/ 4卷
/ 03期
关键词
:
ALPHA-AMINO-ACIDS;
OXIDATIVE CYCLIZATION;
UNACTIVATED ALKENES;
NATURAL OCCURRENCE;
EFFICIENT ACCESS;
CARBENE-TRANSFER;
GOLD;
HYDROAMINATION;
CYCLOISOMERIZATION;
COMPLEXES;
D O I
:
10.1039/c2sc21914j
中图分类号
:
O6 [化学];
学科分类号
:
0703 ;
摘要
:
A novel stereoselective and convergent catalytic method for the cyclopropanation of electron-neutral and -rich olefins by sulfonium ylides is reported which unusually proceeds through olefin activation rather than by metal carbene formation.
引用
收藏
页码:1105 / 1110
页数:6
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[1]
Catalytic, asymmetric sulfur ylide-mediated epoxidation of carbonyl compounds: Scope, selectivity, and applications in synthesis
[J].
Aggarwal, VK
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0
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Winn, CL
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Room temperature hydroamination of N-alkenyl ureas catalyzed by a gold(I) N-heterocyclic carbene complex
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←
1
2
3
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9
10
→
共 96 条
[1]
Catalytic, asymmetric sulfur ylide-mediated epoxidation of carbonyl compounds: Scope, selectivity, and applications in synthesis
[J].
Aggarwal, VK
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
Aggarwal, VK
;
Winn, CL
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
Winn, CL
.
ACCOUNTS OF CHEMICAL RESEARCH,
2004,
37
(08)
:611
-620
[2]
Alternative synthetic methods through new developments in catalysis by gold
[J].
Arcadi, Antonio
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Aquila, Dept Chem Chem Engn & Mat, I-67010 Coppito, AQ, Italy
Univ Aquila, Dept Chem Chem Engn & Mat, I-67010 Coppito, AQ, Italy
Arcadi, Antonio
.
CHEMICAL REVIEWS,
2008,
108
(08)
:3266
-3325
[3]
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[J].
Aubert, Corinne
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
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Aubert, Corinne
;
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论文数:
0
引用数:
0
h-index:
0
机构:
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Fensterbank, Louis
;
Garcia, Pierre
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Garcia, Pierre
;
Malacria, Max
论文数:
0
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0
h-index:
0
机构:
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Malacria, Max
;
Simonneau, Antoine
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Univ Paris 06, UPMC, Inst Parisien Chim Mol, CNRS,UMR 7201, F-75005 Paris, France
Simonneau, Antoine
.
CHEMICAL REVIEWS,
2011,
111
(03)
:1954
-1993
[4]
Room temperature hydroamination of N-alkenyl ureas catalyzed by a gold(I) N-heterocyclic carbene complex
[J].
Bender, Christopher F.
论文数:
0
引用数:
0
h-index:
0
机构:
Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA
Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA
Bender, Christopher F.
;
Widenhoefer, Ross A.
论文数:
0
引用数:
0
h-index:
0
机构:
Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA
Duke Univ, PM Gross Chem Lab, Durham, NC 27708 USA
Widenhoefer, Ross A.
.
ORGANIC LETTERS,
2006,
8
(23)
:5303
-5305
[5]
Gold(I)-catalyzed intramolecular hydroamination of unactivated alkenes with carboxamides
[J].
Bender, Christopher F.
论文数:
0
引用数:
0
h-index:
0
机构:
Duke Univ, Paul M Gross Chem Lab, Durham, NC 27706 USA
Duke Univ, Paul M Gross Chem Lab, Durham, NC 27706 USA
Bender, Christopher F.
;
Widenhoefer, Ross A.
论文数:
0
引用数:
0
h-index:
0
机构:
Duke Univ, Paul M Gross Chem Lab, Durham, NC 27706 USA
Duke Univ, Paul M Gross Chem Lab, Durham, NC 27706 USA
Widenhoefer, Ross A.
.
CHEMICAL COMMUNICATIONS,
2006,
(39)
:4143
-4144
[6]
On the Impact of Steric and Electronic Properties of Ligands on Gold(I)-Catalyzed Cycloaddition Reactions
[J].
Benitez, Diego
论文数:
0
引用数:
0
h-index:
0
机构:
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
Benitez, Diego
;
Tkatchouk, Ekaterina
论文数:
0
引用数:
0
h-index:
0
机构:
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
Tkatchouk, Ekaterina
;
Gonzalez, Ana Z.
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
Gonzalez, Ana Z.
;
Goddard, William A., III
论文数:
0
引用数:
0
h-index:
0
机构:
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
Goddard, William A., III
;
Toste, F. Dean
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
CALTECH, Mat & Proc Simulat Ctr, Pasadena, CA 91125 USA
Toste, F. Dean
.
ORGANIC LETTERS,
2009,
11
(21)
:4798
-4801
[7]
Benitez D, 2009, NAT CHEM, V1, P482, DOI [10.1038/NCHEM.331, 10.1038/nchem.331]
[8]
Gold-Catalyzed Oxidative Cyclizations of cis-3-En-1-ynes To Form Cyclopentenone Derivatives
[J].
Bhunia, Sabyasachi
论文数:
0
引用数:
0
h-index:
0
机构:
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Bhunia, Sabyasachi
;
Ghorpade, Satish
论文数:
0
引用数:
0
h-index:
0
机构:
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Ghorpade, Satish
;
Huple, Deepak B.
论文数:
0
引用数:
0
h-index:
0
机构:
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Huple, Deepak B.
;
Liu, Rai-Shung
论文数:
0
引用数:
0
h-index:
0
机构:
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
Liu, Rai-Shung
.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,
2012,
51
(12)
:2939
-2942
[9]
Natural occurrence, syntheses, and applications of cyclopropyl-group-containing α-amino acids.: 2.: 3,4- and 4,5-methanoamino acids
[J].
Brackmann, Farina
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
Brackmann, Farina
;
de Meijere, Armin
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
de Meijere, Armin
.
CHEMICAL REVIEWS,
2007,
107
(11)
:4538
-4583
[10]
Natural occurrence, syntheses, and applications of cyclopropyl-group-containing α-amino acids.: 1.: 1-aminocyclopropanecarboxylic acid and other 2,3-methanoamino acids
[J].
Brackmann, Farina
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
Brackmann, Farina
;
de Meijere, Armin
论文数:
0
引用数:
0
h-index:
0
机构:
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany
de Meijere, Armin
.
CHEMICAL REVIEWS,
2007,
107
(11)
:4493
-4537
←
1
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