Development of an N-heterocyclic carbene ligand based on concept of chiral mimetic

被引：60

作者：

Arao, T ^{[1
]}

Kondo, K ^{[1
]}

Aoyama, T ^{[1
]}

机构：

[1] Nagoya City Univ, Grad Sch Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 09期

关键词：

D O I：

10.1016/j.tetlet.2005.12.098

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Development of a new N-heterocyclic carbene ligand based on the concept of a chiral mimetic is described. In Pd-catalyzed enantioselective intramolecular alpha-arylation of N-(2-bromophenyl)-N-methyl-2-arylpropanamide, (4R,5R)-4,5-diphenyl-l,3diadamantylmethyl-4,5-dihydro-3H-imidazol-1-ium tetrafluoroborate is shown to function as a good N-heterocyclic carbene precursor. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：1417 / 1420

页数：4

共 30 条

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