Improved electrochemical performance of tin-sulfide anodes for sodium-ion batteries

被引：92
|
作者：
Lu, Ying Ching [1 ]
Ma, Chuze [3 ]
Alvarado, Judith [3 ]
Dimov, Nikolay [2 ]
Meng, Ying Shirley [3 ]
Okada, Shigeto [2 ]
机构：
[1] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Dept Chem Engn, Fukuoka 8190395, Japan
[2] Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan
[3] Univ Calif San Diego, Dept NanoEngn, La Jolla, CA 92037 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 33期
基金：
美国国家科学基金会;
关键词：
HIGH-CAPACITY; GRAPHENE NANOCOMPOSITES; THERMAL-PROPERTIES; OXIDE; ELECTRODES; COMPOSITE; INSERTION;
D O I：
10.1039/c5ta03893f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Due to their highly reversible capacity, tin-sulfide-based materials have gained attention as potential anodes for sodium-ion and lithium-ion batteries. Nevertheless, the performance of tin sulfide anodes is much lower than that of tin oxide anodes. The aim of the present investigation is to improve the electrochemical performances of SnS anodes for sodium-ion batteries using conventional organic electrolytes. Three different carbon composite anodes, SnS/reduce graphene oxide (SnS/G), SnS/reduce graphene oxide/hard carbon (SnS/G + C), and SnS/hard carbon (SnS/C), were prepared by hot water bath synthesis followed by mechanical milling. The mechanism of the conversion and alloying reaction was investigated by TEM. The feasibility of SnS anodes was confirmed in a full cell configuration using Na3V2(PO4)(2)F-3 as the cathode.
引用
收藏
页码：16971 / 16977
页数：7
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