Acetylated Modification of Kapok Fiber and Application for Oil Absorption

被引:53
作者
Wang, Jintao [1 ,2 ]
Wang, Aiqin [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Kapok fiber; Pyridine; Acetylated; Oil absorbency; Reusability; HYDROPHOBIC COTTON FIBERS; PENTANDRA L. GAERTN; CHEMICAL-MODIFICATION; SORPTION PROPERTIES; NATURAL FIBERS; SPILL; WOOD; SORBENT; REMOVAL; WATER;
D O I
10.1007/s12221-013-1834-4
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
A novel kapok fiber-based sorbent for oil absorption was successfully prepared by the modification of kapok fiber with acetic anhydride using pyridine as a catalyst. The acetylated kapok fiber was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The effects of volume ratio of pyridine to acetic anhydride, reaction temperature and time on the oil absorbency were investigated. The highest oil absorbency of as-prepared acetylated kapok fiber was 44.0 g/g, 52.5 g/g, and 84.4 g/g for cyclohexane, toluene, and chloroform, respectively. In addition, the oil absorbency for cyclohexane, toluene, and chloroform reduces by 33.9 %, 39.0 %, and 35.7 % after recycling nine times, respectively. Therefore, the natural renewable kapok fiber could replace those of non-biodegradable oil sorbents in removing toxic organic solvents from industrial sewage.
引用
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页码:1834 / 1840
页数:7
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