A three-dimensional chiral crystal structure constructed from a chiral triazolate ligand showing an SrSi2 topology: poly[bis(μ3-3,5-diethyl-1,2,4-triazolato-κ3N1:N2:N4)trisilver nitrate]

被引:3
作者
Jiang, Feng [1 ]
Dai, Lin [1 ]
Shi, Yiqiang [1 ]
Wang, Zhixiang [1 ]
机构
[1] China Pharmaceut Univ, Sch Pharm, Nanjing 211198, Jiangsu, Peoples R China
关键词
crystal structure; metal-organic frameworks; SrSi2; topology; srs net; silver-triazolates; METAL-ORGANIC FRAMEWORKS; RETICULAR CHEMISTRY; NETS; CLUSTERS;
D O I
10.1107/S0108270113029788
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title metal-organic framework (MOF), {[Ag-3(C6H10N3)(2)]NO3}(n), the Ag-I cation is coordinated by two N atoms from two different 3,5-diethyl-1,2,4-triazolate (detz) ligands in a linear configuration. Each Ag-I cation is then connected to two adjacent Ag-I cations via a mu(3)-N-1:N-2:N-4-detrz ligand, resulting in a three-dimensional chiral silver-triazolate structure showing an SrSi2 (srs) net with 10(3) topology.
引用
收藏
页码:1485 / +
页数:6
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