Syntheses, structures and luminescent properties of two novel Zn (II) coordination polymers

被引：11
作者：
Huang, Ya-Ru [1 ]
Gao, Ling-Ling [1 ]
Wang, Xiao-Qing [1 ]
Fan, Li-Ming [1 ]
Hu, Tuo-Ping [1 ]
机构：
[1] North Univ China, Coll Sci, Dept Chem, Taiyuan 030051, Shanxi, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2018年 / 258卷
关键词：
Coordination polymers; Multifunctional ligands; Luminescent property; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; SMALL MOLECULES; LIGAND; COMPLEXES; MANGANESE(II); ZINC;
D O I：
10.1016/j.jssc.2017.12.028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new coordination polymers, namely [Zn(TZMB)](n), (1) and {[Zn(TZMB)](H(2)TZMB)]center dot (C2H5OH)(0.5)(H2O)(2.5)}(n) (2), (H(2)TZMB = 4,4'-(1H-1,2,4-triazol-1-yl)methylene-bis(benzonic acid), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis, elemental analysis (EA), IR spectrum analysis (IR), powder X-ray diffraction (PXRD), and thermogravimetric (TG) analysis. Single X-ray diffraction analysis reveals that complex 1 is a 3D 3,6-connected net with the point symbol of (6(11)0.8(4))(6(3))(2) and complex 2 is a 2D 3-connected net with the point symbol of (6(3)). Furthermore, luminescent properties of complexes 1 and 2 were also investigated in detail.
引用
收藏
页码：854 / 858
页数：5
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