Carbonyl[hydrotris(3,5-dimethylpyrazol-1-yl)-borato]copper(I) acetonitrile solvate

被引：9

作者：

Blake, AJ ^{[1
]}

Carling, DA ^{[1
]}

George, MW ^{[1
]}

Hubberstey, P ^{[1
]}

Garcia, RL ^{[1
]}

Wilson, C ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2002年 / 58卷

关键词：

D O I：

10.1107/S1600536801021730

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Cu(C15H22BN6)(CO)].C2H3N, crystallizes as neutral [Tp*Cu(CO)] {[Tp*](-) = hydrotris(3,5-dimethylpyrazol-1-yl)borate} molecular units and non-coordinated acetonitrile molecules. The distorted tetrahedral coordination geometry of the copper(I) centre comprises the three N atoms of the [Tp*](-) anion [Cu-N 2.033 (2)-2.054 (2) Angstrom] and the C atom of the carbon monoxide molecule [Cu-C 1.785 (4) Angstrom].

引用

页码：m41 / m42

页数：2

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