Solvothermal synthesis and characterization of an open-framework [Me4N]2HgGe4S10

被引：0
作者：
Zhu, YC [1 ]
Baiyin, MH
Liu, X
Jia, CY
Liu, XY
An, YL
机构：
[1] Dalian Univ Technol, Dept Chem, Dalian 116024, Peoples R China
[2] Jilin Univ, Key Lab Inorgan Synth & Preparat, Changchun 130012, Peoples R China
来源：
ACTA CHIMICA SINICA | 2006年 / 64卷 / 05期
关键词：
solvothermal synthesis; crystal structure; open-framework; thermal stability;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An open-framework [Me4N](2)HgGe4S10 (1) was solvothermally synthesized and characterized by single crystal diffraction, IR and DSC-TG techniques. Compound 1 was built up from supertetrahedra Ge4Se104- and HgS4, and has 1D channels with pore sizes of 0.94 nm X 0.65 nm along direction a or b. TG-DSC results indicated that 1 has a good thermal stability in a nitrogen. Crystal data for 1: M-r=957.55, space group I-4, a = 0.92687(8) nm, c = 1.43739(12) nm, V = 1.23484(18) nm, Z = 2, Mo K alpha lambda = 0.071073 nm, R-1 = 0.057, wR(2) = 0.1374 for 906 reflections with I > 2 sigma(I).
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页码：371 / 374
页数：4
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