Interesting reaction of the indanone oximes under Beckmann rearrangement conditions

被引：22

作者：

Torisawa, Y ^{[1
]}

Nishi, T ^{[1
]}

Minamikawa, J ^{[1
]}

机构：

[1] Otsuka Pharmaceut Co Ltd, Tokushima Factory 2, Proc Res Lab, Tokushima 7710182, Japan

来源：

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS | 2002年 / 12卷 / 03期

关键词：

D O I：

10.1016/S0960-894X(01)00754-5

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

Attempted Beckmann rearrangement of the 6-methoxyindanone oximes in conventional conditions resulted in the formation of the two kinds of unexpected products: 2-sulfonyloxyindanone and the dimeric product. Related rearrangement was also observed in the reaction with RhCl-trifluoromethansulfonic acid system. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：387 / 390

页数：4

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