Salt and sugar: direct synthesis of high surface area carbon materials at low temperatures via hydrothermal carbonization of glucose under hypersaline conditions

被引:91
作者
Fechler, Nina [1 ]
Wohlgemuth, Stephanie-Angelika [1 ]
Jaeker, Philipp [1 ]
Antonietti, Markus [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
关键词
CO2; CAPTURE; NITROGEN; AEROGELS; CHEMISTRY;
D O I
10.1039/c3ta10674h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrothermal carbonization of carbohydrates, here glucose as a model, in salt-water mixtures results in high surface area carbonaceous materials with surface areas up to 650 m(2) g(-1) where porosity is created by aggregation of very small primary nanoparticles, similar to aerogels or high surface area soot. These materials can be obtained by simple washing with water and are useful without further activation processes. Furthermore, no special technical equipment for isolation is needed since the materials are exceptionally stable throughout vacuum drying, thus keeping the overall approach sustainable and very simple.
引用
收藏
页码:9418 / 9421
页数:4
相关论文
共 25 条
  • [1] Advanced carbon aerogels for energy applications
    Biener, Juergen
    Stadermann, Michael
    Suss, Matthew
    Worsley, Marcus A.
    Biener, Monika M.
    Rose, Klint A.
    Baumann, Theodore F.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (03) : 656 - 667
  • [2] Highly selective CO2 capture on N-doped carbon produced by chemical activation of polypyrrole functionalized graphene sheets
    Chandra, Vimlesh
    Yu, Seong Uk
    Kim, Seon Ho
    Yoon, Yo Seob
    Kim, Dong Young
    Kwon, Ah Hyun
    Meyyappan, M.
    Kim, Kwang S.
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (05) : 735 - 737
  • [3] Defluoridation of drinking water using activated titanium rich bauxite
    Das, N
    Pattanaik, P
    Das, R
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 292 (01) : 1 - 10
  • [4] Self-assembled aerogel-like low dielectric constant films
    Fan, HY
    Bentley, HR
    Kathan, KR
    Clem, P
    Lu, YF
    Brinker, CJ
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 285 (1-3) : 79 - 83
  • [5] "Salt Templating": A Simple and Sustainable Pathway toward Highly Porous Functional Carbons from Ionic Liquids
    Fechler, Nina
    Fellinger, Tim-Patrick
    Antonietti, Markus
    [J]. ADVANCED MATERIALS, 2013, 25 (01) : 75 - 79
  • [6] Borax-Mediated Formation of Carbon Aerogels from Glucose
    Fellinger, Tim-Patrick
    White, Robin J.
    Titirici, Maria-Magdalena
    Antonietti, Markus
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (15) : 3254 - 3260
  • [7] Engineering Carbon Materials from the Hydrothermal Carbonization Process of Biomass
    Hu, Bo
    Wang, Kan
    Wu, Liheng
    Yu, Shu-Hong
    Antonietti, Markus
    Titirici, Maria-Magdalena
    [J]. ADVANCED MATERIALS, 2010, 22 (07) : 813 - 828
  • [8] Janz G., 1978, National Standard Reference Data Series (NSRDS)
  • [9] Coherent expanded aerogels and jellies.
    Kistler, SS
    [J]. NATURE, 1931, 127 : 741 - 741
  • [10] Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction
    Liu, Ruili
    Wu, Dongqing
    Feng, Xinliang
    Muellen, Klaus
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (14) : 2565 - 2569