Volumetric properties of aqueous solutions of disodium tartrate and dipotassium L-tartrate at temperatures from 278.15 K to 343.15 K and molalities (0.1, 0.5, and 1.0) mol • kg-1a

被引:11
|
作者
Apelblat, A [1 ]
Manzurola, E
机构
[1] Ben Gurion Univ Negev, Dept Chem Engn, IL-84105 Beer Sheva, Israel
[2] Negev Acad Coll Engn, Dept Chem Engn, Beer Sheva, Israel
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2001年 / 33卷 / 09期
关键词
aqueous solutions of sodium and potassium tartrates; densities; apparent molar volumes; cubic expansion coefficients; apparent molar expansibilities;
D O I
10.1006/jcht.2001.0833
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities of aqueous solutions of disodium tartrate at the molalities (0.09996, 0.49097, and 0.9649) mol (.) k(-1) and of dipotassium L-tartrate at the molalities (0.09993, 0.49769, and 0.9912) mol (.) kg(-1) were determined at 1 K temperature intervals from T = 278.15 K to T = 343.15 K. The densities were used to determine the apparent molar volumes, cubic expansion coefficients, the apparent molar expansibilities, and the second derivatives of the volume with respect to temperature which are related to the derivatives of isobaric heat capacities with respect to pressure. (C) 2001 Academic Press.
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页码:1157 / 1168
页数:12
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