Anion-induced structural varieties of CuII coordination complexes with 3-phenyl-4-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole

被引：0

作者：

Wang, Si ^{[1
]}

Wu, Na ^{[1
]}

Chen, Jing ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin 300387, Peoples R China

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2018年 / 48卷 / 07期

基金：

中国国家自然科学基金;

关键词：

3-phenyl-4-(3-pyridyl)-5-(4-pyridyI)-1,2,4-triazole; Cu-II complexes; anion effect; dichromate capture; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL; CONSTRUCTION; ADSORPTION; EXCHANGE; DESIGN; SYSTEM;

D O I：

10.1080/24701556.2018.1555169

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two Cu-II coordination complexes {[Cu(L-430)(H2O)(2)](NO3)(2)}(n) (I) and {[Cu(L-430)(2)(H2O)(2)](CIO4)(2)(H2O)(0.3)}(n) (II) have been synthesized based on 3-phenyl-4-(3-pyridyl-5-(4-pyridyl)-1,2,4-triazole (L-430) in the presence of different anions (CIF file CCDC nos. 1489348 (I) and 1489349 (II)). Notably, complex I shows a 2D coordination network while polymer II represents a 1D boxlike structure. Further, extended supramolecular architectures are constructed via secondary interactions in both structures. The structural distinction on both compounds fully demonstrates the role of lattice anions NO3- or CIO4- in the assembly of infinite coordination solids. In addition, complex II exhibits some certain efficiency for dichromate (Cr2O72-) capture in the water system. [GRAPHICS] .

引用

页码：334 / 339

页数：6

共 23 条

[11] PRIORITY POLLUTANTS I-A PERSPECTIVE VIEW
KEITH, LH
TELLIARD, WA
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1979, 13 (04) : 416 - 423
[12] From N-substituted thioamides to symmetrical and unsymmetrical 3,4,5-trisubstituted 4H-1,2,4-triazoles:: Synthesis and characterisation of new chelating ligands
Klingele, MH
Brooker, S
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (16) : 3422 - 3434
[13] Halide-ion directed assembly of distinct CdII coordination polymers with 3,5-bis (4-pyridyl)-4-(3-pyridyl)-1,2,4-triazole and azide
Liu, Bo-Lan
Wu, Na
Chen, Jing
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 59 : 9 - 12
[14] pH effect on the assembly of metal-organic architectures
Long, La-Sheng
[J]. CRYSTENGCOMM, 2010, 12 (05): : 1354 - 1365
[15] Anion-Induced Formation of Lanthanide-Organic Chains From 3D Framework Solids. Anion Exchange in a Crystal-to-Crystal Manner
Michaelides, Adonis
Skoulika, Stavroula
[J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (05) : 2039 - 2042
[16] Design and construction of a ferrocene based inclined polycatenated Co-MOF for supercapacitor and dye adsorption applications
Rajak, Richa
Saraf, Mohit
Mohammad, Akbar
Mobin, Shaikh M.
[J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (34) : 17998 - 18011
[17] Sheldrick G. M., 1997, SHELXTL NT VERSION 5
[18] Sheldrick G.M., 1996, SADABS SIEMENS AREA
[19] Anion-induced assembly of two distinct copper(II) coordination polymers with a versatile multidentate N-donor ligand
Wu, Na
Guo, Jian-Hua
Chen, Jing
[J]. TRANSITION METAL CHEMISTRY, 2013, 38 (05) : 489 - 493
[20] Anion-Induced Structures and Luminescent Properties of Chiral Lanthanide-Organic Frameworks Assembled by an Achiral Tripodal Ligand
Yan, Xuhuan
Cai, Zhenghong
Yi, Chunli
Liu, Weisheng
Tan, Minyu
Tang, Yu
[J]. INORGANIC CHEMISTRY, 2011, 50 (06) : 2346 - 2353

← 1 2 3 →