Anion-induced structural varieties of CuII coordination complexes with 3-phenyl-4-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole

被引：0
作者：
Wang, Si [1 ]
Wu, Na [1 ]
Chen, Jing [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin 300387, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2018年 / 48卷 / 07期
基金：
中国国家自然科学基金;
关键词：
3-phenyl-4-(3-pyridyl)-5-(4-pyridyI)-1,2,4-triazole; Cu-II complexes; anion effect; dichromate capture; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL; CONSTRUCTION; ADSORPTION; EXCHANGE; DESIGN; SYSTEM;
D O I：
10.1080/24701556.2018.1555169
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two Cu-II coordination complexes {[Cu(L-430)(H2O)(2)](NO3)(2)}(n) (I) and {[Cu(L-430)(2)(H2O)(2)](CIO4)(2)(H2O)(0.3)}(n) (II) have been synthesized based on 3-phenyl-4-(3-pyridyl-5-(4-pyridyl)-1,2,4-triazole (L-430) in the presence of different anions (CIF file CCDC nos. 1489348 (I) and 1489349 (II)). Notably, complex I shows a 2D coordination network while polymer II represents a 1D boxlike structure. Further, extended supramolecular architectures are constructed via secondary interactions in both structures. The structural distinction on both compounds fully demonstrates the role of lattice anions NO3- or CIO4- in the assembly of infinite coordination solids. In addition, complex II exhibits some certain efficiency for dichromate (Cr2O72-) capture in the water system. [GRAPHICS] .
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收藏
页码：334 / 339
页数：6
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