Synthesis, Crystal Structure and Catalytic Activity Palladium(II) Complexes Containing Bulky Azole Ligands

被引：0

作者：

Zhang Meng-Yao

Zhang Ying-Ying

Zhang Hui-Xin

Wang Shen

Wang Ya-Qi

Zeng Yong-Fei ^{[1
]}

Liu Gui-Yan ^{[1
]}

机构：

[1] Tianjin Normal Univ, Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin Key Lab Struct & Performance Funct Mol, Minist Educ, Tianjin 300387, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 39卷 / 09期

基金：

中国国家自然科学基金;

关键词：

palladium(II) complexes; crystal structure; catalytic activity; Suzuki-Miyaura cross-coupling; SUZUKI-MIYAURA; DESIGN; HECK; VERSATILE; SYSTEMS;

D O I：

10.14102/j.cnki.0254-5861.2011-2660

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bulky azole ligands in combination with PdCl2 provide three new palladium(II) complexes. All these complexes, as pre-catalysts, have high catalytic efficiency for the Suzuki-Miyaura cross-coupling reactions of sterically hindered aryl chlorides and good to high yields are obtained with low catalysts loadings (0.1 mol%) under mild conditions in air.

引用

页码：1669 / 1674

页数：6

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