Synthesis, Crystal Structure and Catalytic Activity Palladium(II) Complexes Containing Bulky Azole Ligands

被引：0
|
作者：
Zhang Meng-Yao
Zhang Ying-Ying
Zhang Hui-Xin
Wang Shen
Wang Ya-Qi
Zeng Yong-Fei [1 ]
Liu Gui-Yan [1 ]
机构：
[1] Tianjin Normal Univ, Key Lab Inorgan Organ Hybrid Funct Mat Chem, Tianjin Key Lab Struct & Performance Funct Mol, Minist Educ, Tianjin 300387, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 39卷 / 09期
基金：
中国国家自然科学基金;
关键词：
palladium(II) complexes; crystal structure; catalytic activity; Suzuki-Miyaura cross-coupling; SUZUKI-MIYAURA; DESIGN; HECK; VERSATILE; SYSTEMS;
D O I：
10.14102/j.cnki.0254-5861.2011-2660
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Bulky azole ligands in combination with PdCl2 provide three new palladium(II) complexes. All these complexes, as pre-catalysts, have high catalytic efficiency for the Suzuki-Miyaura cross-coupling reactions of sterically hindered aryl chlorides and good to high yields are obtained with low catalysts loadings (0.1 mol%) under mild conditions in air.
引用
收藏
页码：1669 / 1674
页数：6
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