Salicylate Ion-Selective Electrode Based on a Calix[4]arene as Ionophore

被引：10

作者：

Ayanoglu, Melek Nur ^{[1
]}

Erturun, H. Elif Kormali ^{[1
]}

Ozel, Ayca Demirel ^{[1
]}

Sahin, Ozlem ^{[2
]}

Yilmaz, Mustafa ^{[2
]}

Kilic, Esma ^{[1
]}

机构：

[1] Ankara Univ, Fac Sci, Dept Chem, TR-06100 Ankara, Turkey

[2] Selcuk Univ, Fac Arts & Sci, Dept Chem, Konya, Turkey

来源：

ELECTROANALYSIS | 2015年 / 27卷 / 07期

关键词：

Salicylate-selective electrode; Calix[4]arene; Potentiometry; Salicylate determination; POTENTIOMETRIC MEMBRANE-ELECTRODE; TANDEM MASS-SPECTROMETRY; NEUTRAL CARRIER; LIQUID-MEMBRANE; SCHIFF-BASE; COPPER(II) COMPLEX; ACID; CALIXARENE; SENSOR; DERIVATIVES;

D O I：

10.1002/elan.201400737

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A salicylate-selective electrode based on calix[4]arene derivative was developed and its response characteristics were investigated. The optimum membrane composition was 1% ionophore, 30% PVC, 69% DOS. The electrode exhibited a Nernstian slope of 58.8 +/- 0.5mV/pSal in the range of 1.0x10(-5)-1.0x10(-1)M with a detection limit of 4.3x10(-6)M at pH4.0, 20 +/- 1 degrees C. The potentiometric response of the electrode in the presence of different anions was investigated by the separate solution method. The lifetime was found at least 4months, and its response time was 5-10s. It was successfully used for the potentiometric determination of salicylate in pharmaceutical preparations.

引用

页码：1676 / 1684

页数：9

共 59 条

[1] Mononuclear copper(II) aspirinate or salicylate complexes with methylimidazoles as biomimetic catalysts for oxidative dealkylation of a hindered phenol, oxidation of catechol and their superoxide scavenging activities [J].

Abuhijleh, A. Latif .

INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (05) :759-762

[2] A phase boundary potential model for apparently "twice-Nernstian" responses of liquid membrane ion-selective electrodes [J].

Amemiya, S ;

Bühlmann, P ;

Umezawa, Y .

ANALYTICAL CHEMISTRY, 1998, 70 (03) :445-454

[3]

Ardakani M. M., 2011, J BRAZIL CHEM SOC, V22, P30

[4]

Ardakani M. M., 2007, J BRAZIL CHEM SOC, V18, P782

[5]

Ardakani M. M., 2008, RUSS J ELECTROCHEM+, V44, P1065

[6]

ARDAKANI MM, 2006, B KOREAN CHEM SOC, V27, P1127

[7]

Bakker E, 1999, ELECTROANAL, V11, P915, DOI 10.1002/(SICI)1521-4109(199909)11:13<915::AID-ELAN915>3.0.CO

[8]

2-J

[9] RECOMMENDATIONS FOR NOMENCLATURE OF ION-SELECTIVE ELECTRODES - (IUPAC RECOMMENDATIONS 1994) [J].

BUCK, RP ;

LINDNER, E .

PURE AND APPLIED CHEMISTRY, 1994, 66 (12) :2527-2536

[10] Highly salicylate-selective membrane electrode based on N,N′-bis-(furaldehyde)-glycine copper(II) complex as neutral carrier [J].

Chai, YQ ;

Ruo, Y ;

Dai, JY ;

Lan, X ;

Gui, GF ;

Sun, AL .

ANALYTICAL LETTERS, 2005, 38 (01) :45-56

← 1 2 3 4 5 6 →