Structures of dinuclear copper(II) complexes bridged by one oximato, one methoxo and one perchlorato ligand, and one oximato and two acetato Ligands

被引：4

作者：

Sakamoto, S

Yatani, A

Kimura, K

Fujii, M

Nakao, Y ^{[1
]}

Kashino, S

Kinoshita, M

Mori, W

机构：

[1] Okayama Univ, Fac Educ, Chem Lab, Okayama 7008530, Japan

[2] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan

[3] Kanagawa Univ, Fac Sci, Dept Chem, Kanagawa 2591205, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2001年 / 74卷 / 12期

关键词：

D O I：

10.1246/bcsj.74.2375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cation of [Cu(L-1(OMe)(ClO4)Cu(bpy)] ClO4 (1) consists of two coppers triply bridged by an oximato, a methoxo, and a perchlorato ligand, where L-1 is 3-[2-(2-pyridyl)ethyl]amino-2-butanone oxime. The geometry around each copper is distorted square-pyramidal. The cation of [Cu(L-1)(OAc)(2)Cu(bpy)]ClO4 (2), consists of two coppers triply bridged by an oximato, an unidentate and a bidentate acetato ligand. The geometry around the coppers is intermediate between a square pyramid and a trigonal bipyramid.

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页码：2375 / 2376

页数：2

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