Interactions of Polyacrylamide with Cationic Surfactants: Thermodynamic and Surface Parameters

被引:10
|
作者
Niranjan, P. S. [1 ]
Shukla, Ratna [1 ]
Upadhyay, Santosh K. [1 ]
机构
[1] Harcourt Butler Technol Inst, Dept Chem, Kanpur 208002, Uttar Pradesh, India
关键词
Interaction; Polyacrylamide; Cetyl trimethyl ammonium bromide; N-cetyl pyridinium chloride; Cationic surfactants; SODIUM DODECYL-SULFATE; MECHANISM; POLYMER;
D O I
10.1007/s11743-011-1276-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The aggregation behaviour of two cationic surfactants, viz. cetyl trimethyl ammonium bromide (CTAB) and N-cetyl pyridinium chloride (CPC), in different concentrations of water-soluble polyacrylamide has been studied in alkaline medium by electrical conductivity and surface tension measurements. A decrease in the critical micelle concentration (CMC) of the surfactant with an increase in polymer content in the mixture was observed. The thermodynamic and surface parameters have been determined and discussed. The results indicate that micellisation becomes more favourable at higher polymer content.
引用
收藏
页码:53 / 57
页数:5
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