Complexes of zinc(II) with N-[2-(hydroxyalkyliminomethyl)phenyl]-4-methylbenzenesulfonamides: synthesis, structure, photoluminescence properties and biological activity

被引：38

作者：

Burlov, A. S. ^{[1
]}

Vlasenko, V. G. ^{[2
]}

Koshchienko, Yu. V. ^{[1
]}

Makarova, N. I. ^{[1
]}

Zubenko, A. A. ^{[3
]}

Drobin, Yu. D. ^{[3
]}

Borodkin, G. S. ^{[1
]}

Metelitsa, A. V. ^{[1
]}

Zubavichus, Ya. V. ^{[4
]}

Garnovskii, D. A. ^{[5
]}

机构：

[1] Southern Fed Univ, Inst Phys & Organ Chem, Stachki Ave 194-2, Rostov Na Donu 344090, Russia

[2] Southern Fed Univ, Inst Phys, Stachki Ave 194, Rostov Na Donu 344090, Russia

[3] North Caucasian Zonal Sci Res Vet Inst, Rostov Highway 0, Novocherkassk 346421, Russia

[4] NRC Kurchatov Inst, 1 Acad Kurchatov Sq, Moscow 123182, Russia

[5] Russian Acad Sci, Southern Sci Ctr, Chekhova Ave 41, Rostov Na Donu 344006, Russia

来源：

POLYHEDRON | 2018年 / 144卷

关键词：

Azomethines; Zinc complexes; UV-Vis spectra; TD-DFT; Biological activity; SCHIFF-BASE; DNA-BINDING; ELECTROLUMINESCENT PROPERTIES; COPPER(II) COMPLEXES; CYTOTOXIC ACTIVITY; CRYSTAL-STRUCTURE; ZN(II) COMPLEXES; METAL-COMPLEXES; LIGAND; PYRAZOLE;

D O I：

10.1016/j.poly.2018.01.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a series of zinc(II) complexes with Schiff bases products of condensation of 2-tosylamonobenzaldehide with various aminoalcohols containing aliphatic spacers of a variable length (CH2)(n) (n = 2-6) was performed. All compounds were characterized with C, H, N elemental analysis, FT-IR, H-1 NMR, X-ray absorption spectroscopy, UV-Vis and photoluminescence data. The local atomic structures of complexes were determined by X-ray absorption spectroscopy from analysis of EXAFS and XANES of Zn K-edges. The electronic absorption spectra, photoluminescence, and biological activities of the complexes were investigated. The assignments of the experimental UV-Vis spectra of zinc(II) complexes have been carried out by Time-Dependent Density Functional Theory TD-DFT calculations. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：249 / 258

页数：10

共 50 条

[1]

AKIMOTO T, 1979, CHEM PHARM BULL, V27, P424

[2]

[Anonymous], 2004, Determination of the sensitivity of microorganisms to antibacterial drugs: Methodological guidelines

[3]

[Anonymous], 1979, RUSS CHEM REV+, DOI DOI 10.1070/RC1979V048N07ABEH002389

[4] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE [J].

BECKE, AD .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5648-5652

[5] Methylene spacer regulated variation in structures and magnetic properties in copper(II) compounds with O, N, O donor Schiff bases [J].

Bhowmik, Prasanta ;

Aliaga-Alcalde, Nuria ;

Gomez, Veronica ;

Corbella, Montserrat ;

Chattopadhyay, Shouvik .

POLYHEDRON, 2013, 49 (01) :269-276

[6] New Ferro- and Antiferromagnetic Complexes of Tridentate Azomethines with Copper [J].

Burlov, A. S. ;

Ikorskii, V. N. ;

Nikolaevskii, S. A. ;

Koshchienko, Yu. V. ;

Vlasenko, V. G. ;

Zubavichus, Ya. V. ;

Uraev, A. I. ;

Vasil'chenko, I. S. ;

Garnovskii, D. A. ;

Borodkin, G. S. ;

Garnovskii, A. D. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (10) :1566-1572

[7] Molecular design of new magnetically active copper complexes with heteroaromatic Schiff bases and azo compounds [J].

Burlov, A. S. ;

Uraev, A. I. ;

Ikorskii, V. N. ;

Nikolaevskii, S. A. ;

Koshchienko, Yu. V. ;

Vasil'chenko, I. S. ;

Garnovskii, D. A. ;

Vlasenko, V. G. ;

Zubavichus, Ya. V. ;

Divaeva, L. N. ;

Borodkin, G. S. ;

Garnovskii, A. D. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (06) :1230-1235

[8] New magnetoactive copper complexes with Schiff's bases [J].

Burlov, A. S. ;

Koshchienko, Yu. V. ;

Ikorskii, V. N. ;

Vlasenko, V. G. ;

Zarubin, I. A. ;

Uraev, A. I. ;

Vasil'chenko, I. S. ;

Garnovskii, D. A. ;

Borodkin, G. S. ;

Nikolaevskii, S. A. ;

Garnovskii, A. D. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (07) :1065-1070

[9]

Burlov A.S., 2015, ELECTROLUMINESCENT O, P228

[10] Synthesis, structure, photo- and electroluminescent properties of bis{(4-methyl-N-[2-[(E)-2-pyridyliminomethyl] phenyl]benzenesulfonamide} zinc(II) [J].

Burlov, Anatolii S. ;

Mal'tsev, Eugenii I. ;

Vlasenko, Valery G. ;

Garnovskii, Dmitrii A. ;

Dmitriev, Artem V. ;

Lypenko, Dmitrii A. ;

Vannikov, Anatoly V. ;

Dorovatovskii, Pavel V. ;

Lazarensko, Vladimir A. ;

Zubavichus, Yan V. ;

Khrustalev, Victor N. .

POLYHEDRON, 2017, 133 :231-237

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