Characterization of luminous-cubic boron-nitride single-crystals doped with Eu3+ and Tb3+ ions -: art. no. 211913

被引：19

作者：

Nakayama, A ^{[1
]}

Taniguchi, T ^{[1
]}

Kubota, Y ^{[1
]}

Watanabe, K ^{[1
]}

Hishita, S ^{[1
]}

Kanda, H ^{[1
]}

机构：

[1] Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan

来源：

APPLIED PHYSICS LETTERS | 2005年 / 87卷 / 21期

基金：

日本学术振兴会;

关键词：

D O I：

10.1063/1.2135886

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Incorporation of Eu3+ and Tb3+ ions into single crystals of cubic boron nitride (c-BN) has been performed by mixing these fluorides into a solvent for crystal growth of c-BN under high pressure. This method consequently brings luminous features into c-BN. The doped c-BN single crystals show no discernible structural changes in their matrices, while their elements are incorporated into the whole of crystals in atomic scale. Photoluminescence spectra of c-BN:Eu and c-BN:Tb exhibit the intra-4f electron transitions of Eu3+ and Tb3+ ions, starting from their excitation levels, D-5(0) and D-5(4), respectively. (c) 2005 American Institute of Physics.

引用

页码：1 / 3

页数：3

共 10 条

[1] LUMINESCENCE AND CHARGE COMPENSATION IN SNO2-TB3+ [J].

CRABTREE, DF .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1975, 8 (17) :2097-2102

[2] SOLVENT EFFECTS OF FLUORIDES IN CUBIC BN HIGH-PRESSURE SYNTHESIS [J].

KOBAYASHI, T .

MATERIALS RESEARCH BULLETIN, 1979, 14 (12) :1541-1551

[3] Visible emission from N-rich turbostratic boron nitride thin films doped with Eu, Tb, and Tm [J].

Liu, QL ;

Xu, FF ;

Tanaka, T .

APPLIED PHYSICS LETTERS, 2002, 81 (21) :3948-3950

[4]

Mishima O, 2000, ELECTRIC REFRACTORY MATERIALS, P495

[5] SIMPLE DEVICE FOR LUMINESCENCE PETROGRAPHY [J].

SIPPEL, RF .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1965, 36 (11) :1556-&

[6] Defect characterization of cBN single crystals grown under HP/HT [J].

Taniguchi, T ;

Watanabe, K ;

Koizumi, S .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 2004, 201 (11) :2573-2577

[7] Spontaneous nucleation of cubic boron nitride single crystal by temperature gradient method under high pressure [J].

Taniguchi, T ;

Yamaoka, S .

JOURNAL OF CRYSTAL GROWTH, 2001, 222 (03) :549-557

[8] Visible cathodoluminescence from Eu-implanted single- and polycrystal c-BN annealed under high-temperature, high-pressure conditions [J].

Vetter, U ;

Hofsäss, H ;

Taniguchi, T .

APPLIED PHYSICS LETTERS, 2004, 84 (21) :4286-4288

[9]

Vetter U, 2003, MATER RES SOC SYMP P, V744, P555

[10] SINTERED SUPERHARD MATERIALS [J].

WENTORF, RH ;

DEVRIES, RC ;

BUNDY, FP .

SCIENCE, 1980, 208 (4446) :873-880

← 1 →