Study on the electron transfer properties of self-assembled viologen monolayers using QCA

被引:0
作者
Lee, DY
Shin, HK
Kwon, YS
Park, SH
Qian, DJ
机构
[1] Dong A Univ, Dept Elect Engn, Pusan 604714, South Korea
[2] Dong A Univ, Dept Port & Logist Syst, Pusan 604714, South Korea
[3] Fudan Univ, Inst Adv Mat, Shanghai 200433, Peoples R China
关键词
cyclic voltammetry (CV); quartz crystal microbalance (QCM); self-assembly; viologen;
D O I
10.1080/15421400500369385
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The self-assembled monolayers of alkane derivatives with sulfur containing head groups on gold substrates have been widely examined recently, since the binding between S atoms and Au surface is strong. We could know it was formed monolayer onto QCM surface by self-assembly from resonant frequency shift using QCA. The measured frequency shift for V8SH was about 351 Hz. From this value, the adsorption mass was about 375 ng. The EQCM measurements revealed the anions transfer during reduction and oxidation, respectively. From the EQCM data, the well-defined shape peaks were nearly equal charges by cyclic voltammetry.
引用
收藏
页码:149 / 154
页数:6
相关论文
共 9 条
[1]   SURFACE-ENHANCED RESONANCE RAMAN-SCATTERING FROM METHYLVIOLOGEN AT A SILVER ELECTRODE - EVIDENCE FOR 2 DISTINCT ADSORPTION INTERACTIONS [J].
FENG, Q ;
YUE, WN ;
COTTON, TM .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (05) :2082-2091
[2]   Quartz crystal microbalance investigation of the interaction of bacterial toxins with ganglioside containing solid supported membranes [J].
Janshoff, A ;
Steinem, C ;
Sieber, M ;
elBaya, A ;
Schmidt, MA ;
Galla, HJ .
EUROPEAN BIOPHYSICS JOURNAL WITH BIOPHYSICS LETTERS, 1997, 26 (03) :261-270
[3]   Stabilization of the assemblies of short alkyl chain asymmetric viologens on alkanethiol-coated electrodes [J].
John, SA ;
Ohsaka, T .
ELECTROCHIMICA ACTA, 1999, 45 (07) :1127-1133
[4]   Quartz crystal microbalance and electrochemical studies on a viologen thiol incorporated in phospholipid self-assembled monolayers [J].
Nakamura, N ;
Huang, HX ;
Qian, DJ ;
Miyake, J .
LANGMUIR, 2002, 18 (15) :5804-5809
[5]   Determining the self-assembling and redox process of a viologen monolayer by electrochemical quartz crystal microbalance [J].
Ock, JY ;
Shin, HK ;
Qian, DJ ;
Miyake, J ;
Kwon, YS .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2004, 43 (4B) :2376-2380
[6]   The electrochemical studies on a self-assembled viologen monolayer using quartz crystal microbalance [J].
Ock, JY ;
Shin, HK ;
Kwon, YS ;
Song, SH ;
Chang, SM ;
Qian, DJ ;
Miyake, J .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2003, 407 :525-530
[7]   Electrochemical reactions in adsorption of organosulfur molecules on gold and silver: Potential dependent adsorption [J].
Paik, WK ;
Eu, S ;
Lee, K ;
Chon, S ;
Kim, M .
LANGMUIR, 2000, 16 (26) :10198-10205
[8]   Electrochemical study of reversible hydrogenase reaction of Desulfovibrio vulgaris cells with methyl viologen as an electron carrier [J].
Tatsumi, H ;
Takagi, K ;
Fujita, M ;
Kano, K ;
Ikeda, T .
ANALYTICAL CHEMISTRY, 1999, 71 (09) :1753-1759
[9]   Formation and structure of self-assembled monolayers [J].
Ulman, A .
CHEMICAL REVIEWS, 1996, 96 (04) :1533-1554