Template-free synthesis and assembly of single-crystalline tungsten oxide nanowires and their gas-sensing properties

被引：362
作者：
Polleux, J
Gurlo, A
Barsan, N
Weimar, U
Antonietti, M
Niederberger, M
机构：
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[2] Univ Tubingen, Inst Phys & Theoret Chem, D-72086 Tubingen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 02期
关键词：
nanowires; organic-inorganic hybrid composites; oxides; sensors; tungsten;
D O I：
10.1002/anie.200502823
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nonaqueous approach that involves the reaction of tungsten isopropoxide with benzyl alcohol leads to tungsten oxide nanowire bundles without the use of any additional structure-directing templates. The bundles consist of crystalline nanowires with highly uniform diameters of about 1 nm and aspect ratios exceeding 500 (see picture). Gas-sensing tests show a high sensitivity to NO2. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：261 / 265
页数：5
相关论文
共 46 条
  • [1] Photocatalytic oxidation of gaseous toluene on anatase TiO2 catalyst:: mechanistic aspects and FT-IR investigation
    Augugliaro, V
    Coluccia, S
    Loddo, V
    Marchese, L
    Martra, G
    Palmisano, L
    Schiavello, M
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1999, 20 (01) : 15 - 27
  • [2] Tungsten-oxide thin films as novel materials with high sensitivity and selectivity to NO2, O3, and H2S -: Part II:: Application as gas sensors
    Berger, O
    Hoffmann, T
    Fischer, WJ
    Melev, V
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2004, 15 (07) : 483 - 493
  • [3] Benzyl alcohol oxidation in supercritical carbon dioxide: spectroscopic insight into phase behaviour and reaction mechanism
    Caravati, M
    Grunwaldt, JD
    Baiker, A
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2005, 7 (02) : 278 - 285
  • [4] Synthesis and electrochromic properties of mesoporous tungsten oxide
    Cheng, W
    Baudrin, E
    Dunn, B
    Zink, JI
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (01) : 92 - 97
  • [5] Solvothermal synthesis of tungsten oxide nanorod/nanowire/nanosheet
    Choi, HG
    Jung, YH
    Kim, DK
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (06) : 1684 - 1686
  • [6] Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts
    Comini, E
    Faglia, G
    Sberveglieri, G
    Pan, ZW
    Wang, ZL
    [J]. APPLIED PHYSICS LETTERS, 2002, 81 (10) : 1869 - 1871
  • [7] Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices
    Duan, XF
    Huang, Y
    Cui, Y
    Wang, JF
    Lieber, CM
    [J]. NATURE, 2001, 409 (6816) : 66 - 69
  • [8] Oxide materials for development of integrated gas sensors - A comprehensive review
    Eranna, G
    Joshi, BC
    Runthala, DP
    Gupta, RP
    [J]. CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 2004, 29 (3-4) : 111 - 188
  • [9] Investigations of nonstoichiometric tungsten oxide nanoparticles
    Frey, GL
    Rothschild, A
    Sloan, J
    Rosentsveig, R
    Popovitz-Biro, R
    Tenne, R
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2001, 162 (02) : 300 - 314
  • [10] Electrochromic tungsten oxide films: Review of progress 1993-1998
    Granqvist, CG
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 60 (03) : 201 - 262
12345