Constructing multi-cluster copper(I) halides using conformationally flexible ligands

被引：21
作者：
Yu, Muxin [1 ,2 ]
Liu, Caiping [2 ]
Li, Shengchang [2 ]
Zhao, Yunfang [2 ]
Lv, Jiangquan [1 ]
Zhuo, Zhu [2 ,3 ]
Jiang, Feilong [2 ]
Chen, Lian [2 ]
Yu, Yunlong [1 ]
Hong, Maochun [2 ]
机构：
[1] Fujian Jiangxia Univ, Organ Optoelect Engn Res Ctr Fujians Univ, Coll Elect & Informat Sci, Fuzhou 350108, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[3] Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen 361021, Fujian, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 53期
基金：
国家重点研发计划;
关键词：
IODIDE CLUSTER; COORDINATION POLYMERS; STRUCTURAL DIVERSITY; PHOTOLUMINESCENCE; LUMINESCENCE; EMISSION; THERMOCHROMISM; CUBANE; CU4I4; MOF;
D O I：
10.1039/d0cc02472d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three unprecedented multi-cluster copper(I) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(I)-halide clusters in one system, which opens a new way for the construction of multi-Cu(I)-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.
引用
收藏
页码：7233 / 7236
页数：4
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