ThCr2Si2 structure type: The "perovskite" of intermetallics

被引：68

作者：

Shatruk, Michael ^{[1
]}

机构：

[1] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2019年 / 272卷

基金：

美国国家科学基金会;

关键词：

Intermetallics; Structure type; Phase transitions; Superconductivity; Magnetism; Mixed valence; Heavy fermions; DOMINANT ANTIFERROMAGNETIC COMPONENTS; 1ST-ORDER PHASE-TRANSITIONS; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; NEUTRON-DIFFRACTION; HIDDEN ORDER; PHOSPHIDES CACO2P2; TERNARY PHOSPHIDES; SITE PREFERENCES; ELECTRON COUNT;

D O I：

10.1016/j.jssc.2019.02.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This work provides a brief review of the crystal structure, compositional scope, structural phase transitions, superconductivity, magnetism, and heavy-fermion behavior in the vast family of ternary intermetallics that belong to the ThCr2Si2 structure type. The intriguing physical properties observed for a number of ThCr2Si2-type materials are discussed relative to the features of their electronic band structure.

引用

页码：198 / 209

页数：12

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