The 500 °C Isothermal Section of the Mn-Si-Sn Ternary System

被引：0

作者：

Peng, Haoping ^{[1
,2
,3
]}

Zhai, Lei ^{[2
]}

Jiang, Shuai ^{[1
]}

Zhu, Ze ^{[1
]}

Liu, Ya ^{[1
,3
]}

Su, Xuping ^{[1
,3
]}

机构：

[1] Changzhou Univ, Key Lab Mat Surface Sci & Technol Jiangsu Prov, Changzhou 213164, Jiangsu, Peoples R China

[2] Changzhou Univ, Jiangsu Key Lab Oil & Gas Storage & Transportat T, Changzhou 213164, Jiangsu, Peoples R China

[3] Changzhou Univ, Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213164, Jiangsu, Peoples R China

来源：

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION | 2020年 / 41卷 / 06期

基金：

美国国家科学基金会;

关键词：

intermetallics; Mn-Si-Sn; phase equilibria; THERMODYNAMIC DESCRIPTION; SELECTIVE OXIDATION; CRYSTAL-STRUCTURE; PHASE-EQUILIBRIA; GE-MN; STEEL; MANGANESE; LIQUID; ZN;

D O I：

10.1007/s11669-020-00842-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mn and Si are common elements in steel and have an important influence on the performance of steel. To analyze the intermetallic compounds formed in tin-base solder welding process, the Mn-Si-Sn alloys were prepared and annealed at 500 degrees C for 30 days. The phase equilibria in the Mn-Si-Sn system at 500 degrees C were studied by electron microscopy equipped with energy-dispersive spectrometry and x-ray diffraction. 12 three-phase regions were well determined in the Mn-Si-Sn system at 500 degrees C, and no ternary compound was found. The binary compound Mn5Si2, which is controversial in the literature, was not observed in the present study. Mn2-xSn (Mn1.8Sn) and Mn3Sn2 phases were detected by XRD rather than the Mn2Sn phase in this work. The solubility of Si in Mn3Sn, Mn2-xSn, Mn3Sn2, and MnSn2 was measured to be 0.7, 1.2, 1.2, and 0.4 at.%, respectively. And the Sn solubility in R-Mn6Si, upsilon-Mn9Si2, Mn3Si, MnSi, Mn11Si19 at 500 degrees C is about 0.9, 0.5, 0.3, 0.3 and 0.2 at.%, respectively.

引用

页码：835 / 845

页数：11

共 50 条

[21] The Gd-Al-Si Isothermal Section at 500 °C [J].

Cardinale, Anna Maria ;

Parodi, Nadia .

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION, 2018, 39 (01) :68-73

[22] The 500°C isothermal section of the Al-Dy-Ti ternary system [J].

Zhou, HY ;

Liu, WF ;

Yuan, SL ;

Yan, JL .

JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 336 (1-2) :218-221

[23] The isothermal section of Dy-Co-Cr ternary system at 500 °C [J].

Yao, Qingrong ;

Zhou, Huaiying ;

Tang, Chengying ;

Du, Yong .

JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (02) :234-236

[24] Experimental investigation of the Nd-Al-Si system The isothermal section at 500 °C [J].

Cardinale, Anna Maria ;

Maccio, Daniele ;

Delfino, Stefano ;

Saccone, Adriana .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2011, 103 (01) :103-109

[25] Isothermal section of the Nd-Co-Ti ternary system at 500°C [J].

Yan, J. L. ;

Wei, X. X. ;

Hu, S. L. ;

Gao, C. ;

Zhuang, Y. H. ;

Li, J. Q. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 496 (1-2) :169-173

[26] The 500°C isothermal section of the Nd-Al-Ti ternary system [J].

Zhou, HY ;

Yao, QR ;

Yuan, SL .

JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 381 (1-2) :137-139

[27] The isothermal section at 400°C of the Nd-Cu-Sn ternary system [J].

Riani, P ;

Fornasini, ML ;

Marazza, R ;

Mazzone, D ;

Zanicchi, G ;

Ferro, R .

INTERMETALLICS, 1999, 7 (07) :835-846

[28] Isothermal section at 750°C of the U-Fe-Sn ternary system [J].

Noël, H ;

Gonçalves, AP .

INTERMETALLICS, 2001, 9 (06) :473-479

[29] Isothermal section of the Mg-Al-Mn ternary system at 400°C [J].

Ren, Y. P. ;

Qin, G. W. ;

Pei, W. L. ;

Zhao, H. D. ;

Guo, Y. ;

Li, H. X. ;

Jiang, M. ;

Hao, S. M. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 479 (1-2) :237-241

[30] Isothermal section of the phase diagram of the Ce-Pt-Si ternary system at 600 °C [J].

Gribanov, A ;

Seropegin, YD ;

Tursina, AI ;

Bodak, OI ;

Rogl, P ;

Noël, H .

JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 383 (1-2) :286-289

← 1 2 3 4 5 →