The 500 °C Isothermal Section of the Mn-Si-Sn Ternary System

被引：0

作者：

Peng, Haoping ^{[1
,2
,3
]}

Zhai, Lei ^{[2
]}

Jiang, Shuai ^{[1
]}

Zhu, Ze ^{[1
]}

Liu, Ya ^{[1
,3
]}

Su, Xuping ^{[1
,3
]}

机构：

[1] Changzhou Univ, Key Lab Mat Surface Sci & Technol Jiangsu Prov, Changzhou 213164, Jiangsu, Peoples R China

[2] Changzhou Univ, Jiangsu Key Lab Oil & Gas Storage & Transportat T, Changzhou 213164, Jiangsu, Peoples R China

[3] Changzhou Univ, Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213164, Jiangsu, Peoples R China

来源：

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION | 2020年 / 41卷 / 06期

基金：

美国国家科学基金会;

关键词：

intermetallics; Mn-Si-Sn; phase equilibria; THERMODYNAMIC DESCRIPTION; SELECTIVE OXIDATION; CRYSTAL-STRUCTURE; PHASE-EQUILIBRIA; GE-MN; STEEL; MANGANESE; LIQUID; ZN;

D O I：

10.1007/s11669-020-00842-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mn and Si are common elements in steel and have an important influence on the performance of steel. To analyze the intermetallic compounds formed in tin-base solder welding process, the Mn-Si-Sn alloys were prepared and annealed at 500 degrees C for 30 days. The phase equilibria in the Mn-Si-Sn system at 500 degrees C were studied by electron microscopy equipped with energy-dispersive spectrometry and x-ray diffraction. 12 three-phase regions were well determined in the Mn-Si-Sn system at 500 degrees C, and no ternary compound was found. The binary compound Mn5Si2, which is controversial in the literature, was not observed in the present study. Mn2-xSn (Mn1.8Sn) and Mn3Sn2 phases were detected by XRD rather than the Mn2Sn phase in this work. The solubility of Si in Mn3Sn, Mn2-xSn, Mn3Sn2, and MnSn2 was measured to be 0.7, 1.2, 1.2, and 0.4 at.%, respectively. And the Sn solubility in R-Mn6Si, upsilon-Mn9Si2, Mn3Si, MnSi, Mn11Si19 at 500 degrees C is about 0.9, 0.5, 0.3, 0.3 and 0.2 at.%, respectively.

引用

页码：835 / 845

页数：11

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