Kinetic and thermodynamic control by chemical bond rearrangement on a Si(001) surface

被引：20
|
作者：
Hamai, C [1 ]
Takagi, A [1 ]
Taniguchi, M [1 ]
Matsumoto, T [1 ]
Kawai, T [1 ]
机构：
[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 11期
关键词：
D O I：
10.1002/anie.200352074
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Changing the force: The driving force that determines the product distribution for acetone adsorbed on the Si(001) surface can be changed from kinetic (producing a four-member-ring species; see scheme) to thermodynamic (producing the dissociation species) upon raising the surface temperature. The results show that the binding of organic molecules to the Si(001) surface is in fact reversible.
引用
收藏
页码：1349 / 1352
页数：4
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