A thermodynamic view on solvent effects of selected SN2 reactions

被引：0
|
作者：
Dabbit, O [1 ]
Kadri, S [1 ]
Wasif, S [1 ]
Khalil, A [1 ]
Salama, SB [1 ]
机构：
[1] Univ Aleppo, Fac Sci, Aleppo, Syria
来源：
ASIAN JOURNAL OF CHEMISTRY | 1999年 / 11卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The present work describes the role of solvents on the kinetics and thermodynamics of closely related S-N(2) reactions of primary, secondary and tertiary iodoalkanes in pure and mixed solvents.
引用
收藏
页码：1296 / 1306
页数：11
相关论文
共 50 条
  • [21] STEREOCHEMISTRY OF SN2' REACTIONS
    DRENTH, W
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1967, 86 (03): : 318 - &
  • [22] Steric Effects of Solvent Molecules on SN2 Substitution Dynamics
    Liu, Xu
    Xie, Jing
    Zhang, Jiaxu
    Yang, Li
    Hase, William L.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (08): : 1885 - 1892
  • [23] THE SN2' REACTION .3. STRUCTURE AND SN2' REACTIONS OF THE HALOCODIDES
    STORK, G
    CLARKE, FH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (18) : 4619 - 4624
  • [24] ANALYSIS OF SOLVENT EFFECT ON SN2 REACTIONS BY DIFFERENT THEORETICAL-MODELS
    ALEMAN, C
    MASERAS, F
    LLEDOS, A
    DURAN, M
    BERTRAN, J
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1989, 2 (08) : 611 - 622
  • [25] SOLVENT EFFECT ON EQUILIBRIA AND SN2 REACTIONS OF NON-CHARGED SPECIES
    TANAKA, M
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1975, 96 (4-6): : 239 - 244
  • [26] EFFECTS OF ALKYL-GROUPS ON RATES OF SN2 REACTIONS
    DETAR, DF
    JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (25): : 5174 - 5176
  • [27] Steric effects in SN2 reactions.: The influence of microsolvation
    Mohamed, AA
    Jensen, F
    JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (13): : 3259 - 3268
  • [28] ABSENCE OF STERIC EFFECTS ON THE LEAVING GROUP IN SN2 REACTIONS
    ELIEL, EL
    GERBER, RP
    TETRAHEDRON LETTERS, 1961, (14) : 473 - 476
  • [29] SN2 REACTIONS IN GAS-PHASE - NUCLEOPHILICITY EFFECTS
    DOUGHERTY, RC
    ROBERTS, JD
    ORGANIC MASS SPECTROMETRY, 1974, 8 (JAN): : 81 - 83
  • [30] The Interplay between Steric and Electronic Effects in SN2 Reactions
    Fernandez, Israel
    Frenking, Gernot
    Uggerud, Einar
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (09) : 2166 - 2175
12345