Positive effects of the residual templates within the MCM-41 mesoporous silica channels in the metal-catalyzed reactions

被引：13
作者：
Mori, Kohsuke [1 ,2 ]
Yamaguchi, Takuya [1 ]
Ikurumi, Shohei [1 ]
Yamashita, Hiromi [1 ,2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Div Mat & Mfg Sci, Suita, Osaka 5650871, Japan
[2] Kyoto Univ, Unit Elements Strategy Initiat Catalysts & Batter, Katsura, Kyoto 6158520, Japan
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 89期
关键词：
AEROBIC OXIDATION;
D O I：
10.1039/c3cc46448b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
As-synthesized Pd/MCM-41 and Au/MCM-41 including the residual SDA organic templates, cetyltrimethylammonium bromide (CTABr), within the mesoporous channels exhibit superior catalytic activities than the conventionally calcined ones without templates, owing to the stabilizing effect of metal nanoparticles, concentration effect of organic substrates and co-catalyst effect due to the basic properties.
引用
收藏
页码：10468 / 10470
页数：3
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