Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures

被引：26

作者：

Ohgo, Y ^{[1
]}

Chiba, Y

Hashizume, D

Uekusa, H

Ozeki, T

Nakamura, M

机构：

[1] Toho Univ, Sch Med, Dept Chem, Ota Ku, Tokyo 1438540, Japan

[2] Toho Univ, Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748510, Japan

[3] Toho Univ, Grad Sch Sci, Div Biomol Sci, Funabashi, Chiba 2748510, Japan

[4] RIKEN, Mol Characterizat Team, Wako, Saitama 3510198, Japan

[5] Tokyo Inst Technol, Dept Chem & Mat Sci, Tokyo 1528551, Japan

[6] Toho Univ, Grad Sch Sci, Div Chem, Funabashi, Chiba 2748510, Japan

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 18期

关键词：

D O I：

10.1039/b601412g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel spin transition between S=5/2 and S=3/2 has been observed for the first time in five-coordinate, highly saddled iron(III) porphyrinates by EPR and SQUID measurements at extremely low temperatures.

引用

页码：1935 / 1937

页数：3

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