Catalytic application of recyclable silica-supported bismuth(III) chloride in the benzo[N,N]-heterocyclic condensation

被引：23

作者：

Aghapoor, Kioumars ^{[1
]}

Mohsenzadeh, Farshid ^{[1
]}

Shakeri, Atena ^{[1
]}

Darabi, Hossein Reza ^{[1
]}

Ghassemzadeh, Mitra ^{[1
]}

Neumueller, Bernhard ^{[2
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, Nano & Organ Synth Lab, Tehran 1496813151, Iran

[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 743卷

关键词：

BiCl3/SiO2; Heterogeneous Lewis acid catalyst; Benzo[N; N]-heterocyclic condensation; SOLID ACID CATALYST; ORGANIC-SYNTHESIS; QUINOXALINE DERIVATIVES; ROOM-TEMPERATURE; HETEROGENEOUS CATALYSIS; EFFICIENT; NANOPARTICLES; CHEMISTRY; WATER; 1,4-DI-N-OXIDE;

D O I：

10.1016/j.jorganchem.2013.06.037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silica-supported bismuth(III) chloride (BiCl3/SiO2) has been successfully employed in the condensation of 1,2-dicarbonyls with a variety of arene-1,2-diamines bearing either electron withdrawing or donating functional groups. The catalyzed reaction proceeded smoothly under ambient temperature in methanol to give the corresponding quinoxaline and pyrido[2,3-b]pyrazine compounds in good to excellent yields. The catalyst exhibited remarkable reusable activity and higher catalytic performance than homogeneous BiCl3. A plausible mechanism for the catalytic action of BiCl3/SiO2 has been introduced. Moreover, the crystal structure of the prepared unsymmetrical benzo[N,N]-heterocycles has been determined by single crystal X-ray diffraction. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：170 / 178

页数：9

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