Combining ionic liquids and polyethylene glycols to boost the hydrophobic-hydrophilic range of aqueous biphasic systems

被引：75

作者：

Pereira, Jorge F. B. ^{[1
]}

Rebelo, Luis Paulo N. ^{[2
]}

Rogers, Robin D. ^{[3
,4
]}

Coutinho, Joao A. P. ^{[1
]}

Freire, Mara G. ^{[1
,2
]}

机构：

[1] Univ Aveiro, CICECO, Dept Quim, P-3810193 Aveiro, Portugal

[2] UNL, Inst Tecnol Quim & Biol, P-2780901 Oeiras, Portugal

[3] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA

[4] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2013年 / 15卷 / 45期

关键词：

HUMAN-SERUM ALBUMIN; POLY(ETHYLENE GLYCOL); 2-PHASE SYSTEMS; EXTRACTION; WATER; SOLUBILITY; PARTITION; BEHAVIOR; SALTS;

D O I：

10.1039/c3cp53701c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work reveals, for the first time, that polymer-ionic-liquid-based aqueous biphasic systems (ABS) exhibit a much wider hydrophilic-hydrophobic range than conventional systems reported to date. Three probe dyes were used to demonstrate that either the polymer-rich or the ionic-liquid-rich layer can serve as the most hydrophobic phase. It was found that the phase polarities can be easily tuned by the choice of an appropriate ionic liquid.

引用

页码：19580 / 19583

页数：4

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