An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

被引:270
作者
Weng, Zhiqiang [1 ,2 ]
He, Weiming [1 ,2 ]
Chen, Chaohuang [1 ,2 ]
Lee, Richmond [3 ]
Tan, Davin [3 ]
Lai, Zhiping [3 ]
Kong, Dedao [1 ,2 ]
Yuan, Yaofeng [1 ,2 ]
Huang, Kuo-Wei [3 ]
机构
[1] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
[2] Fuzhou Univ, Fujian Prov Key Lab Photocatalysis, State Key Lab Breeding Base, Fuzhou 350002, Peoples R China
[3] KAUST, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
基金
中国国家自然科学基金;
关键词
copper; cross-coupling; C?S bonds; trifluoromethylthiolation; ALPHA-FLUORINATED ETHERS; CATALYZED TRIFLUOROMETHYLATION; BORONIC ACIDS; BOND FORMATION; OXIDATIVE TRIFLUOROMETHYLATION; REDUCTIVE ELIMINATION; CONVENIENT SYNTHESIS; ROOM-TEMPERATURE; TERMINAL ALKYNES; SULFIDES;
D O I
10.1002/anie.201208432
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of copper(I) trifluoromethyl thiolate complexes have been synthesized from the reaction of CuF2 with Me3SiCF 3 and S8 (see scheme; Cu red, F green, N blue, S yellow). These air-stable complexes serve as reagents for the efficient conversion of a wide range of aryl halides into the corresponding aryl trifluoromethyl thioethers in excellent yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1548 / 1552
页数:5
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