{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N",N"′}bis(trifluoro-methanesulfanato-κO)copper(II)

被引：5
|
作者：
Coles, Simon J. [1 ]
Sengul, Abdurrahman [2 ]
Kurt, Ozgur [2 ]
Altin, Safinaz [2 ]
机构：
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[2] Zonguldak Karaelmas Univ, Fac Arts & Sci, Dept Chem, TR-67100 Zonguldak, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1107/S1600536808033151
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A discrete neutral Cu-II complex, [Cu(CF3SO3)(2)(C16H18N4)], has been derived from the symmetrical tetradentate Schiff base, N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine. The copper centre assumes a tetragonally distorted pseudo-octahedral geometry with the O atoms of two trifluoromethanesulfonate anions coordinated weakly in the axial positions. The Cu-N distances lie in the range 1.941 (3)-2.011 (3) angstrom and the Cu-O distances are 2.474 (3) and 2.564 (3) angstrom.
引用
收藏
页码：M1435 / U827
页数：13
相关论文
共 50 条
  • [41] N,N′-bis(4-bromobenzylidene)ethane-1,2-diamine
    Fun, Hoong-Kun
    Mirkhani, Valiollah
    Kia, Reza
    Vartooni, Akbar Rostami
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1374 - U1209
  • [42] N,N′-Bis(4-nitrobenzylidene)ethane-1,2-diamine
    Sun, YX
    You, ZL
    Zhu, HL
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : O1707 - O1708
  • [43] Bis{N-methyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine}zinc bis(perchlorate)
    Wang, Chen-Yi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1038 - U394
  • [44] [mu-N,N'-Bis(2-aminoethyl) ethane-1,2-diamine-kappa N-4(1),N-1':N-2,N-2']bis{[N,N'-bis(2-aminoethyl)ethane-1,2-diamine-kappa N-4,N',N",N"']cadmium} tetrakis(perchlorate)
    Goudarziafshar, Hamid
    Abbasityula, Yunes
    Eigner, Vaclav
    Dusek, Michal
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1153 - +
  • [45] [N,N′-Bis(4-chlorobenzyl)ethane-1,2-diamine]dichloridozinc(II)
    Yang, Shu-Ping
    Han, Li-Jun
    Wang, Da-Qi
    Xia, Hai-Tao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M62 - U623
  • [46] N,N′-Bis(2-aminobenzyl)ethane-1,2-diamine
    de Barbarin, Cecilia Rodriguez
    Bernes, Sylvain
    Najera, Blanca
    Elizondo, Perla
    Cerda, Patricia
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O549 - O550
  • [47] N,N′-bis(2-thienylmethylene)ethane-1,2-diamine
    Wang, Da-Qi
    Wang, Qiang
    Xiao, Li-Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4865 - U6525
  • [48] N,N'-bis(2-iodobenzylidene)ethane-1,2-diamine
    Fun, Hoong-Kun
    Kia, Reza
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1870 - U3288
  • [49] {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ3N,N′,N"}bis(thiocyanato-κN)copper(II)
    Gwaram, Nura Suleiman
    Hisham, Nurul Azimah Ikmal
    Khaledi, Hamid
    Ali, Hapipah Mohd
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M58 - U661
  • [50] {N′-[1-(2-Pyridyl)ethylidene-κN]benzohydrazidato-κ2N′,O}{N′-[1-(2-pyridyl)ethylidene-κN]benzohydrazide-κ2N′,O}copper(II) trichloroacetate
    Datta, Amitabha
    Chuang, Nien-Tsu
    Wen, Yun-Sheng
    Huang, Jui-Hsien
    Sheu, Shiann-Cherng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1388 - U843
12345