{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4N,N′,N",N"′}bis(trifluoro-methanesulfanato-κO)copper(II)

被引：5
|
作者：
Coles, Simon J. [1 ]
Sengul, Abdurrahman [2 ]
Kurt, Ozgur [2 ]
Altin, Safinaz [2 ]
机构：
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
[2] Zonguldak Karaelmas Univ, Fac Arts & Sci, Dept Chem, TR-67100 Zonguldak, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1107/S1600536808033151
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A discrete neutral Cu-II complex, [Cu(CF3SO3)(2)(C16H18N4)], has been derived from the symmetrical tetradentate Schiff base, N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine. The copper centre assumes a tetragonally distorted pseudo-octahedral geometry with the O atoms of two trifluoromethanesulfonate anions coordinated weakly in the axial positions. The Cu-N distances lie in the range 1.941 (3)-2.011 (3) angstrom and the Cu-O distances are 2.474 (3) and 2.564 (3) angstrom.
引用
收藏
页码：M1435 / U827
页数：13
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